Chapter 2: Problem 82
Suppose that, in an alternate universe, the possible values of ml are the integer values including 0 ranging from -l -1 to l +1 (instead of simply -l to +l). How many orbitals exist in each sublevel? a. s sublevel b. p sublevel c. d sublevel
Short Answer
Expert verified
The s sublevel has 3 orbitals, the p sublevel has 5 orbitals, and the d sublevel has 7 orbitals.
Step by step solution
01
Understanding the New ml Values
First, recognize that the question describes an alternate universe where the magnetic quantum number, ml, includes all integer values in the range from -(l + 1) to +(l + 1), instead of the usual range from -l to +l. Normally, the number of possible ml values is given by the formula '2l + 1', but in this alternate universe, we need to account for the extra two possible values.
02
Calculating Orbitals for the s Sublevel
For the s sublevel, l = 0. According to the given range, ml can take on values from -(0 + 1) to +(0 + 1), that is, -1 to +1. Count the integer values in this range to find the number of orbitals.
03
Calculating Orbitals for the p Sublevel
For the p sublevel, l = 1. According to the given range, ml values span from -(1 + 1) to +(1 + 1), that is, -2 to +2. Count the integer values in this range to find the number of orbitals.
04
Calculating Orbitals for the d Sublevel
For the d sublevel, l = 2. According to the given range, ml values span from -(2 + 1) to +(2 + 1), that is, -3 to +3. Count the integer values in this range to find the number of orbitals.
05
Summary of Orbital Counts
Tally the number of possible ml values within each range calculated in the previous steps to determine the total number of orbitals for each sublevel.
Unlock Step-by-Step Solutions & Ace Your Exams!
-
Full Textbook Solutions
Get detailed explanations and key concepts
-
Unlimited Al creation
Al flashcards, explanations, exams and more...
-
Ads-free access
To over 500 millions flashcards
-
Money-back guarantee
We refund you if you fail your exam.
Over 30 million students worldwide already upgrade their learning with Vaia!
Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Magnetic Quantum Number
The magnetic quantum number, denoted as \( m_l \), plays a critical role in determining the orientation of electron orbitals within a magnetic field. Under normal quantum mechanics within our universe, for a given sublevel with angular momentum quantum number \( l \), the \( m_l \) values range from \(-l\) to \(+l\), including zero. This creates a set of discrete and quantized orientations for electron orbitals.
For example, in the case of a p sublevel (where \( l = 1 \)), the magnetic quantum number \( m_l \) normally would have three possible values: -1, 0, and +1. These correspond to the three different p orbitals each with a unique orientation in space. The concept provides a fundamental understanding of how electrons are distributed around the nucleus and how these distributions affect chemical properties and behavior.
For example, in the case of a p sublevel (where \( l = 1 \)), the magnetic quantum number \( m_l \) normally would have three possible values: -1, 0, and +1. These correspond to the three different p orbitals each with a unique orientation in space. The concept provides a fundamental understanding of how electrons are distributed around the nucleus and how these distributions affect chemical properties and behavior.
Electron Orbitals
Electron orbitals are regions in an atom where there is a high probability of finding electrons. These orbitals are defined by a set of quantum numbers that describe the energy, shape, and orientation of the orbital. Orbitals are often visualized as cloud-like shapes in various orientations around the nucleus.
Orbitals come in different shapes and sizes, named s, p, d, f, and so on, each with its own characteristic shape. The s orbital is spherical, p orbitals are dumbbell-shaped, d orbitals are more complex, and the pattern continues with each successive type of orbital. The arrangement and complexity of electron orbitals play a fundamental role in shaping the periodic properties of the elements and the structure of the periodic table itself.
Orbitals come in different shapes and sizes, named s, p, d, f, and so on, each with its own characteristic shape. The s orbital is spherical, p orbitals are dumbbell-shaped, d orbitals are more complex, and the pattern continues with each successive type of orbital. The arrangement and complexity of electron orbitals play a fundamental role in shaping the periodic properties of the elements and the structure of the periodic table itself.
Sublevel Orbitals
Sublevel orbitals are divisions within electron shells grouped by the angular momentum quantum number, \( l \). These sublevels are categorized as s, p, d, or f sublevels, corresponding to \( l \) values of 0, 1, 2, and 3, respectively. The number of orbitals in a sublevel is given by the formula \( 2l + 1 \), which dictates how many discrete spatial orientations are available for electrons within that sublevel.
The distinction among sublevels lies in the increasing complexity of the orbitals' shape and the larger number of orbitals as one moves from s to f sublevels. This increase impacts the way electrons are arranged in atoms, which in turn influences chemical bonding and molecular structure. For instance, the p sublevel, with three orbitals (px, py, pz), can house up to six electrons, allowing elements in the p block of the periodic table to exhibit a variety of valences.
The distinction among sublevels lies in the increasing complexity of the orbitals' shape and the larger number of orbitals as one moves from s to f sublevels. This increase impacts the way electrons are arranged in atoms, which in turn influences chemical bonding and molecular structure. For instance, the p sublevel, with three orbitals (px, py, pz), can house up to six electrons, allowing elements in the p block of the periodic table to exhibit a variety of valences.
Quantum Mechanics in Chemistry
Quantum mechanics in chemistry is the foundational framework for understanding atomic and molecular structure and reactivity. It provides the mathematical and conceptual basis for the behavior of electrons in atoms, which directly influences the formation and properties of chemical bonds.
In quantum chemistry, the wave-like nature of particles is described by wavefunctions, from which quantum numbers, like the magnetic quantum number \( m_l \), can be derived. These numbers describe not just the energy of an electron in its orbital, but also its angular momentum and orientation in space. Quantum mechanics dictate that electrons exist in quantized energy states, and chemical reactions can be viewed as the reorganization of these states. This quantum understanding is integral for predicting the outcomes of chemical reactions, the color of compounds, their magnetism, and even their pharmacological properties.
In quantum chemistry, the wave-like nature of particles is described by wavefunctions, from which quantum numbers, like the magnetic quantum number \( m_l \), can be derived. These numbers describe not just the energy of an electron in its orbital, but also its angular momentum and orientation in space. Quantum mechanics dictate that electrons exist in quantized energy states, and chemical reactions can be viewed as the reorganization of these states. This quantum understanding is integral for predicting the outcomes of chemical reactions, the color of compounds, their magnetism, and even their pharmacological properties.