Chapter 3: Problem 94
Arrange these elements in order of decreasing metallic character: Sr, N, Si, P, Ga, Al.
Short Answer
Expert verified
Sr > Al > Ga > Si > P > N
Step by step solution
01
Identify the Criteria for Metallic Character
Metallic character refers to how easily an atom can lose electrons. It generally increases down a group and decreases across a period in the periodic table. Atoms with fewer shells and closer to the left of the periodic table usually have a higher metallic character.
02
Locate the Elements in the Periodic Table
Find the position of each element in the periodic table to understand their group and period. Strontium (Sr) is in Group 2 and Period 5; Nitrogen (N) is in Group 15 and Period 2; Silicon (Si) is in Group 14 and Period 3; Phosphorus (P) is in Group 15 and Period 3; Gallium (Ga) is in Group 13 and Period 4; Aluminum (Al) is in Group 13 and Period 3.
03
Compare Metallic Character Within the Same Period
Within the same period, metallic character decreases from left to right. So among Si, P, and Al (which are in periods 3 and 4), Al has the most metallic character followed by Si, and then P.
04
Compare Metallic Character Within the Same Group
Within the same group, metallic character increases as you move down. So Ga has a higher metallic character than N, despite being in the same group, because Ga is in a lower period.
05
Combine the Comparisons to Determine Order
Considering both the group and period trends, metals are more metallic than non-metals, and metals on the lower left of the periodic table are more metallic than those above them or to their right. Thus, the order of decreasing metallic character is: Sr > Al > Ga > Si > P > N.
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Periodic Table Trends
Understanding the periodic table is crucial for evaluating the metallic character of elements. Metallic character is one of the key attributes that varies predictably across the periodic table due to the table's arrangement based on atomic number and electron configuration.
As you move from left to right across a period, the metallic character generally decreases. This is because elements progressively gain more protons and electrons, leading to a stronger attraction between the positively charged nucleus and the negatively charged electrons. This makes the atoms less willing to lose electrons, a characteristic trait of metals.
As you move from left to right across a period, the metallic character generally decreases. This is because elements progressively gain more protons and electrons, leading to a stronger attraction between the positively charged nucleus and the negatively charged electrons. This makes the atoms less willing to lose electrons, a characteristic trait of metals.
Vertical Trends
Conversely, as you move down a group, the metallic character increases. This happens because additional electron shells are added, making the outermost electrons farther from the nucleus and therefore, more easily lost. The increased distance results in a weaker attraction between the nucleus and the electrons, which aligns with the tendency of metals to lose electrons and form cations.- Moving across a period (left to right) decreases metallic character.
- Moving down a group (top to bottom) increases metallic character.
Electron Configuration
Electron configuration plays a pivotal role in defining an element's chemical properties, including its metallic character. It refers to the distribution of electrons in an atom's orbitals. For metals, which have few valence electrons, these are loosely held and can be easily lost, leading to classic metallic properties like conductivity and malleability.
Energy Levels and Electron Shells
Elements with a smaller number of electron shells, and thus a valence electron closer to the nucleus, tend to hold on to their electrons more tightly and show less metallic character. As you advance down a group in the periodic table, additional shells are added, making it easier for electrons to be lost, enhancing the metallic character of the element.- Elements with fewer electron shells generally have lower metallic character.
- Valence electrons in metals are often in higher-energy shells, more easily lost.
Chemical Properties
The chemical properties of an element can be profoundly influenced by its metallic character. Metals tend to be good conductors of heat and electricity, are malleable, ductile, and often have a lustrous appearance. These properties are attributable to the ease with which metals can lose their valence electrons, allowing for free-flowing electrons which contribute to conductivity.
Reactivity and Compounds
Metals also typically participate in ionic bonding, as they tend to lose electrons and form positive ions (cations). Metallic character affects reactivity as well; more metallic elements are usually more reactive, especially with nonmetals. For example, the reactivity of alkali metals increases down the group.- High metallic character leads to good conductivity and malleability.
- Metallic elements form cations easily and engage in ionic bonding.
- Reactivity with non-metals increases with metallic character.