Chapter 4: Problem 148
The elements X and Y form a compound that is 40% X and 60% Y by mass. The atomic mass of X is twice that of Y. What is the empirical formula of the compound?
Short Answer
Expert verified
The empirical formula is XY.
Step by step solution
01
Define Variables
Let the atomic mass of Y be represented as M. Therefore, the atomic mass of X will be 2M since it is twice that of Y.
02
Calculate Moles
Use the percentage by mass and the atomic masses to calculate moles. For X, divide 40% by 2M. For Y, divide 60% by M.
03
Simplify the Ratio
To find the empirical formula, simplify the mole ratio of X to Y. This can be done by dividing both mole values found in Step 2 by the smallest number of moles.
04
Determine the Empirical Formula
If the ratio from Step 3 is 1:1, the empirical formula will be XY. If another simple whole number ratio is obtained, multiply the subscripts to get the empirical formula.
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Stoichiometry
Stoichiometry is the branch of chemistry that deals with the quantitative relationships between the reactants and products in chemical reactions. It is a foundational concept for understanding how chemical reactions occur and how to calculate the amounts of substances involved. The calculations are based on the balanced chemical equation and the principle of conservation of mass, which states that matter is neither created nor destroyed in a chemical reaction.
For instance, when determining an empirical formula, stoichiometry allows us to compute the simplest whole-number ratio of atoms within a compound based on mass percentages and atomic masses.
For instance, when determining an empirical formula, stoichiometry allows us to compute the simplest whole-number ratio of atoms within a compound based on mass percentages and atomic masses.
Mole Concept
The mole concept is central to stoichiometry and provides a way of measuring the amount of substance. One mole is 6.022 x 1023 particles of that substance, which is known as Avogadro's number. The significance of the mole lies in its ability to relate the macroscopic mass of a substance to its microscopic composition (atoms, molecules, or formula units).
For the exercise on empirical formula calculation, the mole concept is used to convert the mass percentages into a molar ratio. Since the compound is 40% element X and 60% Y, converting these percentages to moles involves dividing by their respective atomic masses. This then allows for determination of the simplest whole number ratio between the two elements.
For the exercise on empirical formula calculation, the mole concept is used to convert the mass percentages into a molar ratio. Since the compound is 40% element X and 60% Y, converting these percentages to moles involves dividing by their respective atomic masses. This then allows for determination of the simplest whole number ratio between the two elements.
Atomic Mass
The atomic mass of an element is a weighted average that reflects the various isotopes of the element and their abundance. It is measured in atomic mass units (amu), where one amu is defined as one twelfth of the mass of a carbon-12 atom. This atomic mass is crucial when converting between grams and moles.
In the exercise provided, knowledge of the atomic masses of elements X and Y is essential for calculating the empirical formula of the compound. Since the atomic mass of X is twice that of Y (2M and M, respectively), these given values help establish the relationship needed to determine the ratio of atoms in the molecule by moles.
In the exercise provided, knowledge of the atomic masses of elements X and Y is essential for calculating the empirical formula of the compound. Since the atomic mass of X is twice that of Y (2M and M, respectively), these given values help establish the relationship needed to determine the ratio of atoms in the molecule by moles.
Percentage Composition
Percentage composition refers to the mass percent of each element in a compound. It is a critical concept when analyzing the composition of compounds and determining empirical formulas. The percentage composition informs us how much of each element is present in a compound compared to the total mass of the compound.
In the context of resolving the given problem, the percentage composition allows us to calculate the part of the mass corresponding to each element in the compound. With 40% of the compound being element X and 60% being Y, these ratios must be converted to moles based on their atomic masses, which then leads to the empirical formula that represents the compound's simplest ratio.
In the context of resolving the given problem, the percentage composition allows us to calculate the part of the mass corresponding to each element in the compound. With 40% of the compound being element X and 60% being Y, these ratios must be converted to moles based on their atomic masses, which then leads to the empirical formula that represents the compound's simplest ratio.