Chapter 4: Problem 48
Write a formula for the ionic compound that forms between each pair of elements. a. silver and chlorine b. sodium and sulfur c. aluminum and sulfur d. potassium and chlorine
Short Answer
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a. AgCl, b. Na2S, c. Al2S3, d. KCl
Step by step solution
01
Determine the Charges of the Ions
Ionic compounds are formed when metals transfer electrons to nonmetals resulting in positively charged cations and negatively charged anions. Silver (Ag) typically forms a +1 cation, chlorine (Cl) forms a -1 anion, sodium (Na) forms a +1 cation, sulfur (S) forms a -2 anion, aluminum (Al) forms a +3 cation, and potassium (K) forms a +1 cation.
02
Pairing Silver and Chlorine
Silver (Ag) and chlorine (Cl) will form an ionic bond where silver is a +1 cation (Ag+) and chlorine is a -1 anion (Cl-). They combine in a 1:1 ratio to balance the charges and form the formula AgCl.
03
Pairing Sodium and Sulfur
Sodium (Na) and sulfur (S) combine with sodium as a +1 cation (Na+) and sulfur as a -2 anion (S^2-). Two sodium ions are needed for every sulfur ion to balance the charges, resulting in the formula Na2S.
04
Pairing Aluminum and Sulfur
Aluminum (Al) forms a +3 cation (Al^3+) and sulfur (S) forms a -2 anion (S^2-). To balance the charges, two aluminum ions are needed for every three sulfur ions, leading to the formula Al2S3.
05
Pairing Potassium and Chlorine
Potassium (K) and chlorine (Cl) will form an ionic bond where potassium is a +1 cation (K+) and chlorine is a -1 anion (Cl-), which combine in a 1:1 ratio to balance the charges and yield the formula KCl.
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Ionic Compounds
Ionic compounds are a class of chemicals that consist of positive and negative ions held together by the strong force of electrical attraction known as ionic bonds. These compounds are often formed when metals react with nonmetals, as seen in the reactions between silver and chlorine or sodium and sulfur.
When a metal atom and a nonmetal atom come into contact, the metal atom tends to lose one or more electrons to the nonmetal atom. This results in the formation of a cation, a positively charged ion, from the metal and an anion, a negatively charged ion, from the nonmetal. The cation and anion then attract each other to form an electrically neutral compound. For instance, in the case of silver and chlorine, a single electron transfer results in the formation of a silver ion (Ag+) and a chloride ion (Cl-), which then combine to create silver chloride (AgCl).
Properties of ionic compounds include high melting and boiling points, their ability to conduct electricity when melted or dissolved in water, and their characteristic crystalline structures.
When a metal atom and a nonmetal atom come into contact, the metal atom tends to lose one or more electrons to the nonmetal atom. This results in the formation of a cation, a positively charged ion, from the metal and an anion, a negatively charged ion, from the nonmetal. The cation and anion then attract each other to form an electrically neutral compound. For instance, in the case of silver and chlorine, a single electron transfer results in the formation of a silver ion (Ag+) and a chloride ion (Cl-), which then combine to create silver chloride (AgCl).
Properties of ionic compounds include high melting and boiling points, their ability to conduct electricity when melted or dissolved in water, and their characteristic crystalline structures.
Cation and Anion Pairing
The process of forming ionic compounds includes the critical step of pairing cations and anions in such a way that the overall charge of the compound is zero. The rule of thumb for achieving this is that the total positive charge must equal the total negative charge. In many cases, cations and anions will combine in a 1:1 ratio, especially when the cation is monovalent (has a charge of +1) and the anion is monovalent (has a charge of -1), as is the case with potassium (K+) and chlorine (Cl-), which combine to form potassium chloride (KCl).
However, when dealing with multivalent ions, which have charges greater than one, the ratio of cations to anions will differ. For example, sodium (Na+), which is a monovalent cation, and sulfur (S2-), a divalent anion, combine in a 2:1 ratio, as two sodium ions are required to balance the charge of one sulfur ion, resulting in the formula Na2S.
However, when dealing with multivalent ions, which have charges greater than one, the ratio of cations to anions will differ. For example, sodium (Na+), which is a monovalent cation, and sulfur (S2-), a divalent anion, combine in a 2:1 ratio, as two sodium ions are required to balance the charge of one sulfur ion, resulting in the formula Na2S.
Balancing Charges in Ionic Compounds
The balancing of charges in ionic compounds is a fundamental aspect of writing their chemical formulas correctly. This involves ensuring that the sum of the charges of all cations equals the sum of the charges of all anions within the compound. The principle of charge balance is based on the scientific law of conservation of charge, which states that the total charge in an isolated system must remain constant.
For instance, aluminum (Al3+), a trivalent cation, requires a certain number of anions to neutralize its charge. When combined with sulfur (S2-), a divalent anion, a simple mathematical calculation can be used: three sulfur ions are required to balance the charge of two aluminum ions, resulting in the formula Al2S3.
By understanding the concept of charge balance, students can more confidently write the formulas for ionic compounds by simply determining the charges of the ions and combining them in the correct ratios to achieve neutrality. This becomes a crucial skill in chemistry, affecting the ability to predict the composition of compounds and their resulting chemical behavior.
For instance, aluminum (Al3+), a trivalent cation, requires a certain number of anions to neutralize its charge. When combined with sulfur (S2-), a divalent anion, a simple mathematical calculation can be used: three sulfur ions are required to balance the charge of two aluminum ions, resulting in the formula Al2S3.
By understanding the concept of charge balance, students can more confidently write the formulas for ionic compounds by simply determining the charges of the ions and combining them in the correct ratios to achieve neutrality. This becomes a crucial skill in chemistry, affecting the ability to predict the composition of compounds and their resulting chemical behavior.