Chapter 5: Problem 27
Write the Lewis structure for each molecule. a. PH3 b. SCl2 c. HI d. CH4
Short Answer
Expert verified
Lewis structures: a. PH3 has a P atom with 3 H atoms singly bonded around it. b. SCl2 has an S atom with 2 Cl atoms singly bonded to it, each with 3 lone pairs, and S has 2 lone pairs. c. HI has a single bond between H and I. d. CH4 has a C atom with 4 H atoms singly bonded around it.
Step by step solution
01
Determine the total number of valence electrons for PH3
Phosphorus (P) has 5 valence electrons and hydrogen (H) has 1 valence electron. Since there are 3 hydrogens, the total number of valence electrons is the sum for all the atoms: 5 + (3 × 1) = 8 valence electrons.
02
Draw the skeletal structure for PH3
Place P in the center and surround it with three H atoms. Single bonds are drawn between P and each H.
03
Complete the octets (or duet for H) for PH3
Hydrogen atoms only need 2 electrons to complete their valence shell (duet rule). Each H is already bonded to P, so their duets are complete and P has 8 electrons fulfilling the octet rule.
04
Determine the total number of valence electrons for SCl2
Sulfur (S) has 6 valence electrons and chlorine (Cl) has 7 valence electrons. Since there are 2 chlorines, the total number of valence electrons is 6 + (2 × 7) = 20 valence electrons.
05
Draw the skeletal structure for SCl2
Place S in the center and surround it with the 2 Cl atoms. Draw single bonds between S and each Cl atom.
06
Complete the octets for SCl2
Each Cl needs 6 more electrons for a total of 8, so place 3 lone pairs (6 electrons) around each Cl. Sulfur, after bonding, has 4 valence electrons and requires 4 more, so place 2 lone pairs around S to complete its octet.
07
Determine the total number of valence electrons for HI
Hydrogen (H) has 1 valence electron, and iodine (I) has 7 valence electrons. The total number of valence electrons is 1 + 7 = 8 valence electrons.
08
Draw the skeletal structure for HI
Connect H and I with a single bond; both their valence requirements are satisfied. Iodine has 7 electrons and needs 1 more to complete its octet, which is satisfied with the bond to hydrogen.
09
Determine the total number of valence electrons for CH4
Carbon (C) has 4 valence electrons and hydrogen (H) has 1 valence electron. Since there are 4 hydrogens, the total number of valence electrons is 4 + (4 × 1) = 8 valence electrons.
10
Draw the skeletal structure for CH4
Place C in the center and surround it with 4 H atoms. Draw single bonds between C and each H.
11
Complete the octets (or duet for H) for CH4
Each H now has a complete duet, and carbon has 8 valence electrons (4 from its own and 4 from H), completing its octet.
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Valence Electrons
Understanding valence electrons is crucial when it comes to predicting how elements will interact with each other to form compounds. Valence electrons are the electrons in the outer shell of an atom that are involved in forming bonds with other atoms. These electrons determine the chemical properties and reactivity of the element. For instance, when we look at phosphorus (P) in the molecule PH3, it has 5 valence electrons in its outer shell. Hydrogen (H), on the other hand, has only 1 valence electron.
When creating Lewis structures, we begin by counting the valence electrons, since they will form the 'dots' around the symbols for the elements in the diagram. In the provided example, for PH3, the total count would be 5 from phosphorus plus 3 from the hydrogen atoms, summing up to 8 valence electrons available for bonding. It's important to remember that although we draw electrons as dots in Lewis structures, in reality, these are dynamic particles, constantly moving in the space around an atom's nucleus.
When creating Lewis structures, we begin by counting the valence electrons, since they will form the 'dots' around the symbols for the elements in the diagram. In the provided example, for PH3, the total count would be 5 from phosphorus plus 3 from the hydrogen atoms, summing up to 8 valence electrons available for bonding. It's important to remember that although we draw electrons as dots in Lewis structures, in reality, these are dynamic particles, constantly moving in the space around an atom's nucleus.
Octet Rule
The octet rule is a chemical rule of thumb that reflects a pattern of stability seen in atoms. According to this rule, atoms are most stable when they have a full valence shell consisting of 8 electrons, which is the configuration of a noble gas. This stability is what atoms 'desire' when they form chemical bonds in compounds.
Using the examples from the exercise, let's delve into PH3. Phosphorus completes its octet when it bonds with three hydrogen atoms. Each hydrogen atom needs only 2 electrons—the duet rule applies here, which is an exception to the octet rule—because hydrogen only has one electron shell. Similarly, for SCl2, both sulfur and chlorine strive to complete their octets by sharing electrons through bonding. It's fascinating how atoms use the electrons as a means to achieve stability, akin to a group of people holding hands to form a circle.
Using the examples from the exercise, let's delve into PH3. Phosphorus completes its octet when it bonds with three hydrogen atoms. Each hydrogen atom needs only 2 electrons—the duet rule applies here, which is an exception to the octet rule—because hydrogen only has one electron shell. Similarly, for SCl2, both sulfur and chlorine strive to complete their octets by sharing electrons through bonding. It's fascinating how atoms use the electrons as a means to achieve stability, akin to a group of people holding hands to form a circle.
Chemical Bonding
The process of chemical bonding is where atoms come together and electrons are shared or transferred between them to form molecules, like the simple cases portrayed in the problem, PH3, SCl2, HI, and CH4. There are mainly two types of bonds featured in such molecules: ionic and covalent.
In covalent bonding, atoms share their valence electrons, as seen in all the examples given. The shared electrons count towards the octet of both atoms involved in the bond. For instance, in methane (CH4), the four hydrogen atoms each share their single electron with carbon to fill its octet, simultaneously completing their own duets.
Understanding the essence of chemical bonds not only helps in drawing accurate Lewis structures but also provides insight into the behavior of molecules and the nature of matter itself. It's akin to understanding that the strength of the bond between individuals in a team determines the team's overall stability and performance.
In covalent bonding, atoms share their valence electrons, as seen in all the examples given. The shared electrons count towards the octet of both atoms involved in the bond. For instance, in methane (CH4), the four hydrogen atoms each share their single electron with carbon to fill its octet, simultaneously completing their own duets.
Understanding the essence of chemical bonds not only helps in drawing accurate Lewis structures but also provides insight into the behavior of molecules and the nature of matter itself. It's akin to understanding that the strength of the bond between individuals in a team determines the team's overall stability and performance.