Explain the following observations: (a) The surface tension of \(\mathrm{CHBr}_{3}\) is greater than that of \(\mathrm{CHCl}_{3} .\) (b) As temperature increases, oil flows faster through a narrow tube. (c) Raindrops that collect on a waxed automobile hood take on a nearly spherical shape. (d) Oil droplets that collect on a waxed automobile hood take on a flat shape.

Short Answer

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(a) CHBr3 has a greater surface tension than CHCl3 due to its larger, heavier bromine atoms, which result in stronger dispersion forces in the molecule. (b) Oil flows faster through a narrow tube as temperature increases because the increase in kinetic energy weakens its intermolecular forces, resulting in decreased viscosity. (c) Raindrops on a waxed automobile hood form a nearly spherical shape due to the surface tension of water, which minimizes the droplet's surface area to achieve a lower energy state. (d) Oil droplets on a waxed automobile hood form a flat shape due to the difference in intermolecular forces between oil and water, causing the oil to spread out and maximize contact with the hydrophilic waxed surface.

Step by step solution

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(a) Comparing surface tension of CHBr3 and CHCl3

Surface tension is a property of liquids that arises due to the unbalanced forces at the surface molecules. In order to compare the surface tension of CHBr3 and CHCl3, we need to consider the strength of the intermolecular forces between the molecules of the two compounds. CHBr3 has larger, heavier bromine atoms as compared to the smaller, lighter chlorine atoms in CHCl3. Larger halogen atoms have more electrons and thus can have stronger dispersion forces. Due to the stronger intermolecular forces in CHBr3, it has a greater surface tension than CHCl3.
02

(b) Viscosity of oil and temperature

Viscosity is a measure of a fluid's resistance to flow, and it is influenced by factors such as temperature and intermolecular forces. As the temperature of the oil increases, the kinetic energy of its particles increases, leading to the weakening of the intermolecular forces between them. This results in a decrease in the oil's viscosity, allowing it to flow faster through the narrow tube as the temperature increases.
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(c) Spherical shape of raindrops on a waxed automobile hood

When raindrops fall on a waxed automobile hood, they form a nearly spherical shape. This occurs due to the surface tension of water, which causes the water molecules to attract each other and minimize the surface area of the droplet. A sphere has the least surface area for a given volume, so the surface tension forces the water droplet to assume a spherical shape to minimize its surface area and achieve a lower energy state.
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(d) Flat shape of oil droplets on a waxed automobile hood

Oil droplets on a waxed automobile hood take on a flat shape due to the difference in the intermolecular forces between oil and water. Oil is hydrophobic and does not mix with water; therefore, it has weaker intermolecular forces with water or other hydrophilic substances like the wax on the automobile hood. These weaker intermolecular forces make it more difficult for oil to form a spherical shape like water droplets and instead cause it to spread out into a flatter shape on the waxed surface, maximizing the contact between oil and wax.

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