Chapter 12: Problem 65
For each of the following pairs of semiconductors, which one will have the larger band gap: (a) CdS or CdTe, (b) GaN or InP, (c) GaAs or InAs?
Chapter 12: Problem 65
For each of the following pairs of semiconductors, which one will have the larger band gap: (a) CdS or CdTe, (b) GaN or InP, (c) GaAs or InAs?
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Get started for free(a) What are the \(\mathrm{C}-\mathrm{C}-\mathrm{C}\) bond angles in diamond? (b) What are they in graphite?
Tin exists in two allotropic forms: Gray tin has a diamond structure, and white tin has a close-packed structure. One of these allotropic forms is a semiconductor with a small band gap while the other is a metal. Which one is which? Which form would you expect to have the longer \(\mathrm{Sn}-\mathrm{Sn}\) bond distance?
A particular form of cinnabar (HgS) adopts the zinc blende structure, Figure \(12.26 .\) The length of the unit cell edge is \(5.852 \AA\). (a) Calculate the density of \(\mathrm{HgS}\) in this form. (b) The mineral tiemmanite (HgSe) also forms a solid phase with the zinc blende structure. The length of the unit cell edge in this mineral is \(6.085 \AA\). What accounts for the larger unit cell length in tiemmanite? (c) Which of the two substances has the higher density? How do you account for the difference in densities?
Gold adopts a face-centered cubic structure with a unit cell edge of \(4.08 \AA\) (Figure 12.11 ). How many gold atoms are there in a sphere that is \(20 \mathrm{nm}\) in diameter? Recall that the volume of a sphere is \(\frac{4}{3} \pi r^{3}\).
An element crystallizes in a body-centered cubic lattice. The edge of the unit cell is \(2.86 \AA,\) and the density of the crystal is \(7.92 \mathrm{~g} / \mathrm{cm}^{3} .\) Calculate the atomic weight of the element.
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