Chapter 13: Problem 18
When ammonium chloride dissolves in water, the solution becomes colder. (a) Is the solution process exothermic or endothermic? (b) Why does the solution form?
Chapter 13: Problem 18
When ammonium chloride dissolves in water, the solution becomes colder. (a) Is the solution process exothermic or endothermic? (b) Why does the solution form?
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Get started for freeCommon laboratory solvents include acetone \(\left(\mathrm{CH}_{3} \mathrm{COCH}_{3}\right),\) methanol \(\left(\mathrm{CH}_{3} \mathrm{OH}\right),\) toluene \(\left(\mathrm{C}_{6} \mathrm{H}_{5} \mathrm{CH}_{3}\right),\) and water. Which of these is the best solvent for nonpolar solutes? Explain.
Calculate the freezing point of a \(0.100 m\) aqueous solution of \(\mathrm{K}_{2} \mathrm{SO}_{4},\) (a) ignoring interionic attractions, and (b) taking interionic attractions into consideration by using the van't Hoff factor (Table 13.4\()\)
How does the lattice energy of an ionic solid affect its solubility in water? [Section 13.1\(]\)
Ascorbic acid (vitamin \(\left.\mathrm{C}, \mathrm{C}_{6} \mathrm{H}_{8} \mathrm{O}_{6}\right)\) is a water-soluble vitamin. A solution containing \(80.5 \mathrm{~g}\) of ascorbic acid dissolved in \(210 \mathrm{~g}\) of water has a density of \(1.22 \mathrm{~g} / \mathrm{mL}\) at \(55^{\circ} \mathrm{C}\). Calculate (a) the mass percentage, (b) the mole fraction, (c) the molality, (d) the molarity of ascorbic acid in this solution.
At ordinary body temperature \(\left(37^{\circ} \mathrm{C}\right)\) the solubility of \(\mathrm{N}_{2}\) in water in contact with air at ordinary atmospheric pressure \((1.0 \mathrm{~atm})\) is \(0.015 \mathrm{~g} / \mathrm{L}\). Air is approximately \(78 \mathrm{~mol} \% \mathrm{~N}_{2}\). Calculate the number of moles of \(\mathrm{N}_{2}\) dissolved per liter of blood, which is essentially an aqueous solution. At a depth of \(100 \mathrm{ft}\) in water, the pressure is \(4.0 \mathrm{~atm}\). What is the solubility of \(\mathrm{N}_{2}\) from air in blood at this pressure? If a scuba diver suddenly surfaces from this depth, how many milliliters of \(\mathrm{N}_{2}\) gas, in the form of tiny bubbles, are released into the bloodstream from each liter of blood?
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