As shown in Table \(15.2, K_{p}\) for the equilibrium
$$
\mathrm{N}_{2}(g)+3 \mathrm{H}_{2}(g) \rightleftharpoons 2 \mathrm{NH}_{3}(g)
$$
is \(4.51 \times 10^{-5}\) at \(450^{\circ} \mathrm{C}\). For each of the mixtures
listed here, indicate whether the mixture is at equilibrium at \(450^{\circ}
\mathrm{C}\). If it is not at equilibrium, indicate the direction (toward
product or toward reactants) in which the mixture must shift to achieve
equilibrium.
(a) \(98 \mathrm{~atm} \mathrm{NH}_{3}, 45 \mathrm{~atm} \mathrm{~N}_{2}, 55
\mathrm{~atm} \mathrm{H}_{2}\)
(b) \(57 \mathrm{~atm} \mathrm{NH}_{3}, 143 \mathrm{~atm} \mathrm{~N}_{2},\) no
\(\mathrm{H}_{2}\)
(c) \(13 \mathrm{~atm} \mathrm{NH}_{2} 27 \mathrm{~atm} \mathrm{~N}_{2} 82
\mathrm{~atm} \mathrm{H}_{2}\)