Chapter 18: Problem 58
Discuss how catalysts can make processes more energy efficient.
Chapter 18: Problem 58
Discuss how catalysts can make processes more energy efficient.
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Get started for freeIt has been pointed out that there may be increased amounts of \(\mathrm{NO}\) in the troposphere as compared with the past because of massive use of nitrogen-containing compounds in fertilizers. Assuming that NO can eventually diffuse into the stratosphere, how might it affect the conditions of life on Earth? Using the index to this text, look up the chemistry of nitrogen oxides. What chemical pathways might \(\mathrm{NO}\) in the troposphere follow?
Distinguish among salt water, freshwater, and groundwater. \([\) Section 18.3\(]\)
A reaction for converting ketones to lactones, called the Bacyer-Villiger
reaction,
Which choice is greener in a chemical process? Explain. (a) A reaction that can be run at \(350 \mathrm{~K}\) for 12 hours without a catalyst or one that can be run at \(300 \mathrm{~K}\) for 1 hour with a catalyst. (b) A reagent for the reaction that can be obtained from corn husks or one that can be obtained from petroleum. (c) \(\mathrm{A}\) process that produces no by-products or one in which the byproducts are recycled for another process.
The enthalpy of evaporation of water is \(40.67 \mathrm{~kJ} / \mathrm{mol}\). Sunlight striking Earth's surface supplies \(168 \mathrm{~W}\) per square meter \((1 \mathrm{~W}=1 \mathrm{watt}=1 \mathrm{~J} / \mathrm{s}) .\) (a) Assuming that evaporation of water is only due to energy input from the Sun, calculate how many grams of water could be evaporated from a 1.00 square meter patch of ocean over a 12 -hour day. (b) The specific heat capacity of liquid water is \(4.184 \mathrm{~J} / \mathrm{g}^{\circ} \mathrm{C}\). If the initial temperature of a 1.00 square meter patch of ocean is \(26^{\circ} \mathrm{C},\) what is its final temperature after being in sunlight for 12 hours, assuming no phase changes and assuming that sunlight penetrates uniformly to depth of \(10.0 \mathrm{~cm}\) ?
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