Chapter 18: Problem 67
What properties of CFCs make them ideal for various commercial applications but also make them a long-term problem in the stratosphere?
Chapter 18: Problem 67
What properties of CFCs make them ideal for various commercial applications but also make them a long-term problem in the stratosphere?
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Get started for freeA first-stage recovery of magnesium from seawater is precipitation of \(\mathrm{Mg}(\mathrm{OH})_{2}\) with \(\mathrm{CaO}\) : \(\mathrm{Mg}^{2+}(a q)+\mathrm{CaO}(s)+\mathrm{H}_{2} \mathrm{O}(l) \longrightarrow \mathrm{Mg}(\mathrm{OH})_{2}(s)+\mathrm{Ca}^{2+}(a q)\) What mass of \(\mathrm{CaO}\), in grams, is needed to precipitate \(1000 \mathrm{lb}\) of \(\mathrm{Mg}(\mathrm{OH})_{2} ?\)
Discuss how catalysts can make processes more energy efficient.
The dissociation energy of a carbon-bromine bond is typically about \(210 \mathrm{~kJ} / \mathrm{mol}\). (a) What is the maximum wavelength of photons that can cause \(\mathrm{C}-\mathrm{Br}\) bond dissociation? (b) Which kind of electromagnetic radiation-ultraviolet, visible, or infrared-does the wavelength you calculated in part (a) correspond to?
Describe the basic goals of green chemistry. [Section 18.5\(]\)
The concentration of \(\mathrm{H}_{2} \mathrm{O}\) in the stratosphere is about \(5 \mathrm{ppm}\). It undergoes photodissociation according to: $$ \mathrm{H}_{2} \mathrm{O}(g) \longrightarrow \mathrm{H}(g)+\mathrm{OH}(g) $$ (a) Write out the Lewis-dot structures for both products and reactant. (b) Using Table \(8.4,\) calculate the wavelength required to cause this dissociation. (c) The hydroxyl radicals, OH, can react with ozone, giving the following reactions: $$ \begin{array}{l} \mathrm{OH}(g)+\mathrm{O}_{3}(g) \longrightarrow \mathrm{HO}_{2}(g)+\mathrm{O}_{2}(g) \\ \mathrm{HO}_{2}(g)+\mathrm{O}(g) \longrightarrow \mathrm{OH}(g)+\mathrm{O}_{2}(g) \end{array} $$ What overall reaction results from these two elementary reactions? What is the catalyst in the overall reaction? Explain.
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