Indicate whether each of the following statements is true or false: (a) If something is oxidized, it is formally losing electrons. (b) For the reaction \(\mathrm{Fe}^{3+}(a q)+\mathrm{Co}^{2+}(a q) \longrightarrow \mathrm{Fe}^{2+}(a q)+\) \(\mathrm{Co}^{3+}(a q), \mathrm{Fe}^{3+}(a q)\) is the reducing agent and \(\mathrm{Co}^{2+}(a q)\) is the oxidizing agent. (c) If there are no changes in the oxidation state of the reactants or products of a particular reaction, that reaction is not a redox reaction.

Short Answer

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(a) True; (b) False; (c) True.

Step by step solution

01

Statement (a)

Is "If something is oxidized, it is formally losing electrons" true or false? In a redox reaction, when a reactant is oxidized, it formally loses electrons as it has an increase in its oxidation state. Therefore, this statement is true.
02

Statement (b)

Is "For the reaction \(\mathrm{Fe}^{3+}(a q)+\mathrm{Co}^{2+}(a q)\longrightarrow \mathrm{Fe}^{2+}(a q)+\mathrm{Co}^{3+}(a q), \mathrm{Fe}^{3+}(a q)\) is the reducing agent and \(\mathrm{Co}^{2+}(a q)\) is the oxidizing agent" true or false? First, identify which elements are being oxidized and which are being reduced: - \(\mathrm{Fe}^{3+}(a q)\) is reduced to \(\mathrm{Fe}^{2+}(a q)\) because its oxidation state decreases from +3 to +2. - \(\mathrm{Co}^{2+}(a q)\) is oxidized to \(\mathrm{Co}^{3+}(a q)\) because its oxidation state increases from +2 to +3. A reducing agent is a substance that causes the reduction of another substance, meaning it provides electrons to the other species. In this case, \(\mathrm{Fe}^{3+}(a q)\) is the species being reduced, and \(\mathrm{Co}^{2+}(a q)\) is the species that is providing the electrons for this reduction to happen, so \(\mathrm{Co}^{2+}(a q)\) is the reducing agent. An oxidizing agent is a substance that causes the oxidation of another substance, meaning it takes electrons from the other species. In this case, \(\mathrm{Co}^{2+}(a q)\) is the species being oxidized, and \(\mathrm{Fe}^{3+}(a q)\) is the species taking electrons from Cobalt, so \(\mathrm{Fe}^{3+}(a q)\) is the oxidizing agent. Therefore, this statement is false because it incorrectly states the roles of \(\mathrm{Fe}^{3+}(a q)\) and \(\mathrm{Co}^{2+}(a q)\).
03

Statement (c)

Is "If there are no changes in the oxidation state of the reactants or products of a particular reaction, that reaction is not a redox reaction" true or false? In a redox reaction, there is always a change in the oxidation state of at least one element in the reactants and products, since the exchange of electrons is occurring in the reaction. If there are no changes in the oxidation states of the elements in a reaction, then it cannot be a redox reaction. Therefore, this statement is true.

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Most popular questions from this chapter

(a) Based on standard reduction potentials, would you expect copper metal to oxidize under standard conditions in the presence of oxygen and hydrogen ions? (b) When the Statue of Liberty was refurbished, Teflon spacers were placed between the iron skeleton and the copper metal on the surface of the statue. What role do these spacers play?

A disproportionation reaction is an oxidation-reduction reaction in which the same substance is oxidized and reduced. Complete and balance the following disproportionation reactions: (a) \(\mathrm{Ni}^{+}(a q) \longrightarrow \mathrm{Ni}^{2+}(a q)+\mathrm{Ni}(s) \quad\) (acidic solution) (b) \(\mathrm{MnO}_{4}^{2-}(a q) \longrightarrow \mathrm{MnO}_{4}^{-}(a q)+\mathrm{MnO}_{2}(s)\) (acidic solution) (c) \(\mathrm{H}_{2} \mathrm{SO}_{3}(a q) \longrightarrow \mathrm{S}(s)+\mathrm{HSO}_{4}^{-}(a q) \quad\) (acidic solution) (d) \(\mathrm{Cl}_{2}(a q) \longrightarrow \mathrm{Cl}^{-}(a q)+\mathrm{ClO}^{-}(a q)\) (basic solution)

A voltaic cell utilizes the following reaction: $$2 \mathrm{Fe}^{3+}(a q)+\mathrm{H}_{2}(g) \longrightarrow 2 \mathrm{Fe}^{2+}(a q)+2 \mathrm{H}^{+}(a q)$$ (a) What is the emf of this cell under standard conditions? (b) What is the emf for this cell when \(\left[\mathrm{Fe}^{3+}\right]=3.50 \mathrm{M}\), \(P_{\mathrm{H}_{2}}=0.95 \mathrm{~atm},\left[\mathrm{Fe}^{2+}\right]=0.0010 \mathrm{M},\) and the \(\mathrm{pH}\) in both half-cells is \(4.00 ?\)

(a) Write the half-reaction that occurs at a hydrogen electrode in acidic aqueous solution when it serves as the anode of a voltaic cell. (b) The platinum electrode in a standard hydrogen electrode is specially prepared to have a large surface area. Why is this important? (c) Sketch a standard hydrogen electrode.

For a spontaneous reaction \(\mathrm{A}(a q)+\mathrm{B}(a q) \longrightarrow \mathrm{A}^{-}(a q)+\) \(\mathrm{B}^{+}(a q),\) answer the following questions: (a) If you made a voltaic cell out of this reaction, what halfreaction would be occurring at the cathode, and what half-reaction would be occurring at the anode? (b) Which half-reaction from (a) is higher in potential energy? (c) What is the sign of \(E_{\text {cell }}^{\circ}\) [ Section 20.3 ]

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