Explain the following observations: (a) \(\mathrm{HNO}_{3}\) is a stronger oxidizing agent than \(\mathrm{H}_{3} \mathrm{PO}_{4}\). (b) Silicon can form an ion with six fluorine atoms, \(\mathrm{SiF}_{6}^{2-}\), whereas carbon is able to bond to a maximum of four, \(\mathrm{CF}_{4}\). (c) There are three compounds formed by carbon and hydrogen that contain two carbon atoms each \(\left(\mathrm{C}_{2} \mathrm{H}_{2}, \mathrm{C}_{2} \mathrm{H}_{4},\right.\) and \(\left.\mathrm{C}_{2} \mathrm{H}_{6}\right),\) whereas silicon forms only one analogous compound \(\left(\mathrm{Si}_{2} \mathrm{H}_{6}\right)\).

Short Answer

Expert verified
The difference in the chemical properties and bonding in the given observations can be explained as follows: (a) HNO3 is a stronger oxidizing agent than H3PO4 due to the higher oxidation state and electronegativity of nitrogen compared to phosphorus, making it more likely to accept electrons. (b) Silicon can form SiF6^2- with six fluorine atoms because of its access to 3d orbitals, allowing for an expanded octet, while carbon is limited to a maximum of four bonded atoms in CF4 due to its available 2s and 2p orbitals. (c) Carbon can form three various compounds with hydrogen (C2H2, C2H4, C2H6) due to its ability to undergo multiple types of hybridization and form single, double, and triple bonds, whereas silicon forms only one analogous compound with hydrogen (Si2H6) as it does not readily form multiple bonds.

Step by step solution

01

Observation (a): HNO3 is a stronger oxidizing agent than H3PO4.

The difference in oxidizing strength between HNO3 and H3PO4 can be attributed to the difference in their structures and the electronegativities of nitrogen and phosphorus. In HNO3, nitrogen has a higher oxidation state (+5) while in H3PO4, phosphorus has a lower oxidation state (+3). In addition, nitrogen is more electronegative than phosphorus. The combined effect of a higher oxidation state and higher electronegativity makes nitrogen more likely to accept electrons, making HNO3 a stronger oxidizing agent compared to H3PO4.
02

Observation (b): SiF6^2- versus CF4

Silicon can bond to six fluorine atoms to form SiF6^2- while carbon can bond to a maximum of four fluorine atoms to form CF4. This difference is due to the fact that silicon, in the third period, has access to its 3d orbitals, which allows for the formation of an expanded octet. This expanded octet enables silicon to accommodate more than four bonded atoms. Carbon, on the other hand, is in the second period and only has 2s and 2p orbitals available for bonding, which limits it to a maximum of four bonded atoms.
03

Observation (c): Compounds of carbon and silicon with hydrogen

Carbon forms three different compounds with hydrogen containing two carbon atoms each (C2H2, C2H4, C2H6), while silicon forms only one analogous compound (Si2H6). The reason behind this difference lies in the multiple types of hybridization that carbon can undergo due to its small size and specific combination of valence electrons, which allows it to form single, double, and triple bonds with other carbon atoms. Silicon, on the other hand, is larger and less electronegative and tends to not form multiple bonds readily. As a result, it can only form one analogous compound with hydrogen, in which silicon atoms are single-bonded to each other.

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Most popular questions from this chapter

When ammonium perchlorate decomposes thermally, the products of the reaction are \(\mathrm{N}_{2}(g), \mathrm{O}_{2}(g), \mathrm{H}_{2} \mathrm{O}(g),\) and \(\mathrm{HCl}(g)\) (a) Write a balanced equation for the reaction. [Hint: You might find it easier to use fractional coefficients for the products.] (b) Calculate the enthalpy change in the reaction per mole of \(\mathrm{NH}_{4} \mathrm{ClO}_{4}\). The standard enthalpy of formation of \(\mathrm{NH}_{4} \mathrm{ClO}_{4}(s)\) is \(-295.8 \mathrm{~kJ}\) (c) When \(\mathrm{NH}_{4} \mathrm{ClO}_{4}(s)\) is employed in solid-fuel booster rockets, it is packed with powdered aluminum. Given the high temperature needed for \(\mathrm{NH}_{4} \mathrm{ClO}_{4}(s)\) decomposition and what the products of the reaction are, what role does the aluminum play? (d) Calculate the volume of all the gases that would be produced at STP, assuming complete reaction of one pound of ammonium perchlorate.

Are the physical properties of \(\mathrm{H}_{2} \mathrm{O}\) different from \(\mathrm{D}_{2} \mathrm{O}\) ? Explain.

Write a balanced net ionic equation for each of the following reactions: (a) Dilute nitric acid reacts with zinc metal with formation of nitrous oxide. (b) Concentrated nitric acid reacts with sulfur with formation of nitrogen dioxide. (c) Concentrated nitric acid oxidizes sulfur dioxide with formation of nitric oxide. (d) Hydrazine is burned in excess fluorine gas, forming \(\mathrm{NF}_{3}\). (e) Hydrazine reduces \(\mathrm{CrO}_{4}^{2-}\) to \(\mathrm{Cr}(\mathrm{OH})_{4}^{-}\) in base (hydrazine is oxidized to \(\mathrm{N}_{2}\) ).

Name the following compounds and assign oxidation states to (a) \(\mathrm{Fe}\left(\mathrm{ClO}_{3}\right)_{3}\) (c) \(\mathrm{XeF}_{6}\) the halogens in them: (b) \(\mathrm{HClO}_{2}\) (d) \(\mathrm{BrF}_{5}\) (e) \(\mathrm{XeOF}_{4}\), (f) \(\mathrm{HIO}_{3}\)

Write the Lewis structure for each of the following species, and indicate the structure of each: (a) \(\mathrm{SeO}_{3}{ }^{2-} ;\) (b) \(\mathrm{S}_{2} \mathrm{Cl}_{2} ;(\mathrm{c})\) chlorosulfonic acid, \(\mathrm{HSO}_{3} \mathrm{Cl}\) (chlorine is bonded to sulfur).

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