Chapter 23: Problem 17
Explain the difference between a diamagnetic substance and a paramagnetic substance.
Chapter 23: Problem 17
Explain the difference between a diamagnetic substance and a paramagnetic substance.
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Get started for freeThe most important oxides of iron are magnetite, \(\mathrm{Fe}_{3} \mathrm{O}_{4},\) and hematite, \(\mathrm{Fe}_{2} \mathrm{O}_{3}\) (a) What are the oxidation states of iron in these compounds? (b) One of these iron oxides is ferrimagnetic, and the other is antiferromagnetic. Which iron oxide is likely to show which type of magnetism? Explain.
Write balanced chemical equations to represent the following observations. (In some instances the complex involved has been discussed previously in the text.) (a) Solid silver chloride dissolves in an excess of aqueous ammonia. (b) The green complex \(\left[\mathrm{Cr}(\mathrm{en})_{2} \mathrm{Cl}_{2}\right] \mathrm{Cl},\) on treatment with water over a long time, converts to a brown-orange complex. Reaction of \(\mathrm{AgNO}_{3}\) with a solution of the product precipitates \(3 \mathrm{~mol}\) of AgCl per mole of Cr present. (Write two chemical equations.) (c) When an NaOH solution is added to a solution of \(\mathrm{Zn}\left(\mathrm{NO}_{3}\right)_{2},\) a precipitate forms. Addition of excess \(\mathrm{NaOH}\) solution causes the precipitate to dissolve. (Write two chemical equations.) (d) A pink solution of \(\mathrm{Co}\left(\mathrm{NO}_{3}\right)_{2}\) turns deep blue on addition of concentrated hydrochloric acid.
Write the formula for each of the following compounds, being sure to use brackets to indicate the coordination sphere: (a) tetraaquadibromomanganese(III) perchlorate (b) bis(bipyridyl) cadmium(II) chloride (c) potassium tetrabromo( ortho-phenanthroline)cobaltate (III) (d) cesium diamminetetracyanochromate(III) (e) tris(ethylenediammine)rhodium(III) tris(oxalato)cobaltate(III)
The molecule dimethylphosphinoethane \(\left[\left(\mathrm{CH}_{3}\right)_{2} \mathrm{PCH}_{2}^{-}\right.\) \(\mathrm{CH}_{2} \mathrm{P}\left(\mathrm{CH}_{3}\right)_{2},\) which is abbreviated dmpe \(]\) is used as a ligand for some complexes that serve as catalysts. A complex that contains this ligand is \(\mathrm{Mo}(\mathrm{CO})_{4}(\) dmpe \() .\) (a) Draw the Lewis structure for dmpe, and compare it with ethylenediammine as a coordinating ligand. (b) What is the oxidation state of Mo in \(\mathrm{Na}_{2}\left[\mathrm{Mo}(\mathrm{CN})_{2}(\mathrm{CO})_{2}(\) dmpe \()\right] ?(\mathrm{c})\) Sketch the structure of the \(\left[\mathrm{Mo}(\mathrm{CN})_{2}(\mathrm{CO})_{2}(\mathrm{dmpe})\right]^{2-}\) ion, including all the pos- sible isomers.
Write the names of the following compounds, using the standard nomenclature rules for coordination complexes: (a) \(\left[\mathrm{Rh}\left(\mathrm{NH}_{3}\right)_{4} \mathrm{Cl}_{2}\right] \mathrm{Cl}\) (b) \(\mathrm{K}_{2}\left[\mathrm{TiCl}_{6}\right]\) (c) \(\mathrm{MoOCl}_{4}\) (d) \(\left[\mathrm{Pt}\left(\mathrm{H}_{2} \mathrm{O}\right)_{4}\left(\mathrm{C}_{2} \mathrm{O}_{4}\right)\right] \mathrm{Br}_{2}\)
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