The average concentration of bromide ion in seawater is \(65 \mathrm{mg}\) of bromide ion per \(\mathrm{kg}\) of seawater. What is the molarity of the bromide ion if the density of the seawater is \(1.025 \mathrm{~g} / \mathrm{mL} ?\)

Short Answer

Expert verified
The molarity of bromide ion in seawater is approximately \(8.34 \times 10^{-4} \, \mathrm{mol/L}\).

Step by step solution

01

Convert the concentration of bromide ion to moles

First, we need to convert the concentration of the bromide ion, given in mg/kg, to moles. To do this, we will use the molar mass of bromide ion (Br⁻), which is approximately 79.90 g/mol. The given concentration of bromide ion is 65 mg of Br⁻ per kg of seawater. We need to convert this into grams and then to moles using the molar mass of Br⁻: \(65 \, mg = 0.065 \, g \, \text{of Br⁻}\). Now, we can convert 0.065 g of Br⁻ to moles of Br⁻ using the molar mass: \(n = \frac{0.065 \, \text{g}}{79.90 \, \text{g/mol}} = 8.1352 \times 10^{-4} \, \text{mol}\). In 1 kg of seawater, there are \(8.1352 \times 10^{-4}\) moles of Br⁻.
02

Convert the mass of seawater to volume

Next, we will convert the mass of seawater (1 kg) to its volume. We are given the density of seawater, which is 1.025 g/mL. To do this, we will use the following equation: Density = Mass / Volume We will first need to convert 1 kg of seawater to grams (1000 g), then solve for the volume in milliliters: \(1.025 \, \text{g/mL} = \frac{1000 \, \text{g}}{V_{mL}}\) Now, we solve for the volume of seawater in milliliters (V_mL): \(V_{mL} = \frac{1000 \, \text{g}}{1.025 \, \text{g/mL}} = 975.61 \, \text{mL}\). Finally, we convert the volume of seawater to liters (V_L): \(V_{L} = \frac{975.61 \, \text{mL}}{1000 \, \text{mL/L}} = 0.97561 \, \text{L}\).
03

Calculate the molarity of bromide ion

Now that we know the number of moles of Br⁻ and the volume of seawater in liters, we can calculate the molarity (M) using the following equation: Molarity (M) = Number of moles of solute / Volume of solution (L) Using the values from the previous steps, we get: \(M = \frac{8.1352 \times 10^{-4} \, \text{mol}}{0.97561 \, \text{L}} = 8.3367 \times 10^{-4} \, \text{mol/L}\). Therefore, the molarity of bromide ion in seawater is approximately \(8.34 \times 10^{-4} \, \mathrm{mol/L}\).

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