Predict whether each of the following compounds is soluble in water: (a) \(\mathrm{AgI},\) (b) \(\mathrm{Na}_{2} \mathrm{CO}_{3},\) (c) \(\mathrm{BaCl}_{2},\) (d) \(\mathrm{Al}(\mathrm{OH})_{3}\), (e) \(\mathrm{Zn}\left(\mathrm{CH}_{3} \mathrm{COO}\right)_{2}\).

Short Answer

Expert verified
In conclusion, the solubility of the given compounds in water are as follows: a) \(\mathrm{AgI}\) - Insoluble b) \(\mathrm{Na}_{2} \mathrm{CO}_{3}\) - Soluble c) \(\mathrm{BaCl}_{2}\) - Soluble d) \(\mathrm{Al}(\mathrm{OH})_{3}\) - Insoluble e) \(\mathrm{Zn}\left(\mathrm{CH}_{3} \mathrm{COO}\right)_{2}\) - Soluble

Step by step solution

01

Solubility Rules

Here are some key solubility rules that will help us in determining the solubility of the compounds: 1. Most alkali metal compounds, i.e., those from Group 1 such as sodium (Na) and potassium (K), are soluble in water. 2. Most nitrates (NO3-), bicarbonates (HCO3-), and chlorides (Cl-), bromides (Br-), and iodides (I-) salts are soluble, except for silver (Ag), lead (Pb), and mercury (Hg) compounds. 3. Sulfates (SO4 2-) are usually soluble, except for barium (Ba), calcium (Ca), and strontium (Sr) sulfates. 4. Most carbonates (CO3 2-), phosphates (PO4 3-), and chromates (CrO4 2-) are insoluble, except when combined with alkali metals. 5. Most hydroxides (OH-) and sulfides (S2-) are insoluble, except when combined with alkali metals or ammonium (NH4+). 6. Some carboxylates (such as acetates CH3COO-) are soluble like sodium and potassium salts. Now, let's use these rules to determine the solubility of the given compounds.
02

Solubility of \(\mathrm{AgI}\)

Using rule 2, most iodide salts are soluble, except for silver (Ag) compounds. So, AgI is insoluble in water.
03

Solubility of \(\mathrm{Na}_{2} \mathrm{CO}_{3}\)

According to rule 4, most carbonates are insoluble, except when combined with alkali metals. Since this compound is formed with sodium (Na), an alkali metal, Na2CO3 is soluble in water.
04

Solubility of \(\mathrm{BaCl}_{2}\)

Considering rule 2, most chloride salts are soluble. Thus, BaCl2 is soluble in water.
05

Solubility of \(\mathrm{Al}(\mathrm{OH})_{3}\)

Using rule 5, most hydroxides are insoluble, except when combined with alkali metals or ammonium. Since this compound has aluminum (not an alkali metal), Al(OH)3 is insoluble in water.
06

Solubility of \(\mathrm{Zn}\left(\mathrm{CH}_{3} \mathrm{COO}\right)_{2}\)

According to rule 6, some carboxylates, such as acetates, are soluble, specifically when they are combined with sodium and potassium salts. Zinc acetate (Zn(CH3COO)2) is soluble in water because acetates are generally soluble in water. In conclusion,: a) AgI - Insoluble b) Na2CO3 - Soluble c) BaCl2 - Soluble d) Al(OH)3 - Insoluble e) Zn(CH3COO)2 - Soluble

Unlock Step-by-Step Solutions & Ace Your Exams!

  • Full Textbook Solutions

    Get detailed explanations and key concepts

  • Unlimited Al creation

    Al flashcards, explanations, exams and more...

  • Ads-free access

    To over 500 millions flashcards

  • Money-back guarantee

    We refund you if you fail your exam.

Over 30 million students worldwide already upgrade their learning with Vaia!

One App. One Place for Learning.

All the tools & learning materials you need for study success - in one app.

Get started for free

Most popular questions from this chapter

We have learned in this chapter that many ionic solids dissolve in water as strong electrolytes, that is, as separated ions in solution. What properties of water facilitate this process? Would you expect ionic compounds to be soluble in elemental liquids like bromine or mercury, just as they are in water? Explain.

The arsenic in a 1.22-g sample of a pesticide was converted to \(\mathrm{AsO}_{4}^{3-}\) by suitable chemical treatment. It was then titrated using \(\mathrm{Ag}^{+}\) to form \(\mathrm{Ag}_{3} \mathrm{AsO}_{4}\) as a precipitate. (a) What is the oxidation state of As in \(\mathrm{AsO}_{4}{ }^{3-} ?\) (b) Name \(\mathrm{Ag}_{3} \mathrm{AsO}_{4}\) by analogy to the corresponding compound containing phosphorus in place of arsenic. (c) If it took \(25.0 \mathrm{~mL}\) of \(0.102 \mathrm{M} \mathrm{Ag}^{+}\) to reach the equivalence point in this titration, what is the mass percentage of arsenic in the pesticide?

Because the oxide ion is basic, metal oxides react readily with acids. (a) Write the net ionic equation for the following reaction: \(\mathrm{FeO}(s)+2 \mathrm{HClO}_{4}(a q) \longrightarrow \mathrm{Fe}\left(\mathrm{ClO}_{4}\right)_{2}(a q)+\mathrm{H}_{2} \mathrm{O}(l)\) (b) Based on the equation in part (a), write the net ionic equation for the reaction that occurs between \(\mathrm{NiO}(s)\) and an aqueous solution of nitric acid.

What mass of \(\mathrm{NaOH}\) is needed to precipitate the \(\mathrm{Cd}^{2+}\) ions from \(35.0 \mathrm{~mL}\) of \(0.500 \mathrm{M} \mathrm{Cd}\left(\mathrm{NO}_{3}\right)_{2}\) solution?

(a) What volume of \(0.115 \mathrm{M} \mathrm{HClO}_{4}\) solution is needed to neutralize \(50.00 \mathrm{~mL}\) of \(0.0875 \mathrm{M} \mathrm{NaOH}\) ? (b) What volume of \(0.128 \mathrm{M} \mathrm{HCl}\) is needed to neutralize \(2.87 \mathrm{~g}\) of \(\mathrm{Mg}(\mathrm{OH})_{2} ?\) (c) If \(25.8 \mathrm{~mL}\) of \(\mathrm{AgNO}_{3}\) is needed to precipitate all the \(\mathrm{Cl}^{-}\) ions in a \(785-\mathrm{mg}\) sample of \(\mathrm{KCl}\) (forming \(\mathrm{AgCl}\) ), what is the molarity of the \(\mathrm{AgNO}_{3}\) solution? (d) If \(45.3 \mathrm{~mL}\) of \(0.108 \mathrm{M} \mathrm{HCl}\) solution is needed to neutralize a solution of KOH, how many grams of KOH must be present in the solution?

See all solutions

Recommended explanations on Chemistry Textbooks

View all explanations

What do you think about this solution?

We value your feedback to improve our textbook solutions.

Study anywhere. Anytime. Across all devices.

Sign-up for free