What mass of \(\mathrm{KCl}\) is needed to precipitate the silver ions from \(15.0 \mathrm{~mL}\) of \(0.200 \mathrm{M} \mathrm{AgNO}_{3}\) solution?

Short Answer

Expert verified
To precipitate the silver ions from \(15.0 \mathrm{~mL}\) of \(0.200 \mathrm{M} \mathrm{AgNO}_{3}\) solution, \(0.2237 \: \mathrm{g}\) of potassium chloride (\(\mathrm{KCl}\)) is needed.

Step by step solution

01

Write the balanced chemical equation

First, we need to write the balanced chemical equation for the reaction between silver nitrate and potassium chloride to form a silver chloride precipitate and potassium nitrate. The balanced equation is: \(AgNO_3 + KCl \rightarrow AgCl_{(s)} + KNO_3\) Notice that the stoichiometric ratio between AgNO₃ and KCl is 1:1.
02

Calculate the moles of silver nitrate

We are given the volume (15.0 mL) and concentration (0.200 M) of the silver nitrate solution. In order to find the moles of silver nitrate, we can use the formula: Moles = Volume × Concentration. Convert the volume to liters and calculate the moles: Moles of \(AgNO_3 = 15.0 \mathrm{~mL} * \frac{1 \mathrm{~L}}{1000 \mathrm{~mL}} * 0.200 \mathrm{M} = 0.00300 \mathrm{~mol}\)
03

Calculate the moles of potassium chloride

We know that the stoichiometric ratio between silver nitrate and potassium chloride is 1:1 from the balanced chemical equation. Therefore, the moles of potassium chloride needed for the reaction will be the same as the moles of silver nitrate. Moles of KCl = Moles of \(AgNO_3 = 0.00300 \mathrm{~mol}\)
04

Calculate the mass of potassium chloride

To find the mass of potassium chloride (KCl), we will use the molecular weight of KCl and the moles calculated in the previous step. The molecular weight of KCl = 39.10 g/mol (K) + 35.45 g/mol (Cl) = 74.55 g/mol Now, calculate the mass of KCl: Mass of KCl = Moles of KCl × Molecular Weight of KCl \( Mass\_of\_KCl = 0.00300 \mathrm{~mol} * 74.55 \frac{g}{\mathrm{mol}} = 0.2237 g \)
05

Final answer

Therefore, 0.2237 grams of potassium chloride (KCl) is needed to completely precipitate the silver ions from 15.0 mL of 0.200 M silver nitrate (AgNO₃) solution.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Chemical Equations
Understanding the language of chemical reactions is fundamental in chemistry, and it starts with chemical equations. A chemical equation represents a chemical reaction where the reactants are listed on the left and the products on the right, separated by an arrow indicating the direction of the reaction. For instance, in the given exercise, the chemical equation is:
\[AgNO_3 + KCl \rightarrow AgCl_{(s)} + KNO_3\]
This tells us that silver nitrate reacts with potassium chloride to yield silver chloride and potassium nitrate. Importantly, the equation must be balanced with the same number of atoms of each element on both sides, reflecting the conservation of mass. A balanced equation also allows us to understand the stoichiometry of the reaction - the quantitative relationship between reactants and products in a chemical reaction.
Molar Mass Calculation
When you're faced with a problem involving chemical compounds, it's critical to know how to calculate molar mass. Molar mass is the weight of one mole of a substance and is expressed in grams per mole (g/mol). It is calculated by summing the atomic masses of all atoms in a molecule of the substance. For example:
\[Molar\ Mass\ of\ KCl = (39.10\ g/mol\ (K)) + (35.45\ g/mol\ (Cl)) = 74.55\ g/mol\]
You can find the atomic masses on the periodic table for each element comprising the compound. Knowing the molar mass is essential because it serves as a conversion factor between grams and moles, enabling you to perform crucial calculations related to the substance's quantity in a reaction.
Precipitation Reactions
Precipitation reactions are a type of chemical reaction where solutions containing different ions produce an insoluble solid, or a precipitate, when mixed. In the context of the exercise, silver nitrate and potassium chloride are aqueous solutions that react to form a precipitate of silver chloride:\[AgNO_3 (aq) + KCl (aq) \rightarrow AgCl_{(s)} + KNO_3 (aq)\]
The subscript 's' in AgCl_{(s)} indicates that silver chloride is the precipitate. Precipitation reactions are critical for understanding solubility, separating substances, and are widely used in various industries including water treatment, medicine, and mining. Recognizing what combinations of ions will form a precipitate is vital for predicting the course of a reaction and for the proper disposal of substances in environmental chemistry.

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Most popular questions from this chapter

Determine the oxidation number of sulfur in each of the following substances: (a) barium sulfate, \(\mathrm{BaSO}_{4},\) (b) sulfurous acid, \(\mathrm{H}_{2} \mathrm{SO}_{3},\) (c) strontium sulfide, \(\mathrm{SrS},\) (d) hydrogen sulfide, \(\mathrm{H}_{2} \mathrm{~S} .\) (e) Based on these compounds what is the range of oxidation numbers seen for sulfur? Is there any relationship between the range of accessible oxidation states and sulfur's position on the periodic table?

(a) How many grams of solute are present in \(15.0 \mathrm{~mL}\) of \(0.736 \mathrm{M} \mathrm{K}_{2} \mathrm{Cr}_{2} \mathrm{O}_{7} ?\) (b) If \(14.00 \mathrm{~g}\) of \(\left(\mathrm{NH}_{4}\right)_{2} \mathrm{SO}_{4}\) is dissolved in enough water to form \(250 \mathrm{~mL}\) of solution, what is the molarity of the solution? (c) How many milliliters of \(0.0455 \mathrm{M} \mathrm{CuSO}_{4}\) contain \(3.65 \mathrm{~g}\) of solute?

Using the activity series (Table 4.5 ), write balanced chemical equations for the following reactions. If no reaction occurs, simply write NR. (a) Iron metal is added to a solution of copper(II) nitrate; (b) zinc metal is added to a solution of magnesium sulfate; (c) hydrobromic acid is added to tin metal; (d) hydrogen gas is bubbled through an aqueous solution of nickel(II) chloride; (e) aluminum metal is added to a solution of cobalt(II) sulfate.

Formic acid, \(\mathrm{HCOOH},\) is a weak electrolyte. What solute particles are present in an aqueous solution of this compound? Write the chemical equation for the ionization of \(\mathrm{HCOOH}\).

(a) What volume of \(0.115 \mathrm{M} \mathrm{HClO}_{4}\) solution is needed to neutralize \(50.00 \mathrm{~mL}\) of \(0.0875 \mathrm{M} \mathrm{NaOH}\) ? (b) What volume of \(0.128 \mathrm{M} \mathrm{HCl}\) is needed to neutralize \(2.87 \mathrm{~g}\) of \(\mathrm{Mg}(\mathrm{OH})_{2} ?\) (c) If \(25.8 \mathrm{~mL}\) of \(\mathrm{AgNO}_{3}\) is needed to precipitate all the \(\mathrm{Cl}^{-}\) ions in a \(785-\mathrm{mg}\) sample of \(\mathrm{KCl}\) (forming \(\mathrm{AgCl}\) ), what is the molarity of the \(\mathrm{AgNO}_{3}\) solution? (d) If \(45.3 \mathrm{~mL}\) of \(0.108 \mathrm{M} \mathrm{HCl}\) solution is needed to neutralize a solution of KOH, how many grams of KOH must be present in the solution?

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