Chapter 5: Problem 23
Identify the force present and explain whether work is being performed in the following cases: (a) You lift a pencil off the top of a desk. (b) A spring is compressed to half its normal length.
Chapter 5: Problem 23
Identify the force present and explain whether work is being performed in the following cases: (a) You lift a pencil off the top of a desk. (b) A spring is compressed to half its normal length.
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Get started for freeConsider the combustion of liquid methanol, \(\mathrm{CH}_{3} \mathrm{OH}(l):\) $$ \begin{aligned} \mathrm{CH}_{3} \mathrm{OH}(l)+\frac{3}{2} \mathrm{O}_{2}(g) \longrightarrow \mathrm{CO}_{2}(g)+2 \mathrm{H}_{2} \mathrm{O}(l) & \\ \Delta H=&-726.5 \mathrm{~kJ} \end{aligned} $$ (a) What is the enthalpy change for the reverse reaction? (b) Balance the forward reaction with whole-number coefficients. What is \(\Delta H\) for the reaction represented by this equation? (c) Which is more likely to be thermodynamically favored, the forward reaction or the reverse reaction? (d) If the reaction were written to produce \(\mathrm{H}_{2} \mathrm{O}(g)\) instead of \(\mathrm{H}_{2} \mathrm{O}(l)\) would you expect the magnitude of \(\Delta H\) to increase, decrease, or stay the same? Explain.
The heat of combustion of fructose, \(\mathrm{C}_{6} \mathrm{H}_{12} \mathrm{O}_{6},\) is \(-2812 \mathrm{~kJ} / \mathrm{mol}\). If a fresh golden delicious apple weighing 4.23 oz \((120 \mathrm{~g})\) contains \(16.0 \mathrm{~g}\) of fructose, what caloric content does the fructose contribute to the apple?
Three common hydrocarbons that contain four carbons are listed here, along with their standard enthalpies of formation: (a) For each of these substances, calculate the molar enthalpy of combustion to \(\mathrm{CO}_{2}(g)\) and \(\mathrm{H}_{2} \mathrm{O}(l) .\) (b) Calculate the fuel value in \(\mathrm{kJ} / \mathrm{g}\) for each of these compounds. \((\mathrm{c})\) For each hydrocarbon, determine the percentage of hydrogen by mass. (d) By comparing your answers for parts (b) and (c), propose a relationship between hydrogen content and fuel value in hydrocarbons.
Imagine a book that is falling from a shelf. At a particular moment during its fall, the book has a kinetic energy of \(24 \mathrm{~J}\) and a potential energy with respect to the floor of \(47 \mathrm{~J} .\) (a) How does the book's kinetic energy and its potential energy change as it continues to fall? (b) What is its total kinetic energy at the instant just before it strikes the floor? (c) If a heavier book fell from the same shelf, would it have the same kinetic energy when it strikes the floor? [Section 5.1]
For the following processes, calculate the change in internal energy of the system and determine whether the process is endothermic or exothermic: (a) A balloon is cooled by removing \(0.655 \mathrm{~kJ}\) of heat. It shrinks on cooling, and the atmosphere does \(382 \mathrm{~J}\) of work on the balloon. (b) A 100.0 -g bar of gold is heated from \(25^{\circ} \mathrm{C}\) to \(50{ }^{\circ} \mathrm{C}\) during which it absorbs \(322 \mathrm{~J}\) of heat. Assume the volume of the gold bar remains constant. (c) The surroundings do \(1.44 \mathrm{~kJ}\) of work compressing gas in a perfectly insulated cylinder.
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