Consider two solutions, the first being \(50.0 \mathrm{~mL}\) of \(1.00
\mathrm{M} \mathrm{CuSO}_{4}\) and the second \(50.0 \mathrm{~mL}\) of \(2.00
\mathrm{MKOH}\). When the two solutions are mixed in a constant-pressure
calorimeter, a precipitate forms and the temperature of the mixture rises from
\(21.5^{\circ} \mathrm{C}\) to \(27.7^{\circ} \mathrm{C}\).
(a) Before mixing, how many grams of Cu are present in the solution of
\(\mathrm{CuSO}_{4} ?\) (b) Predict the identity of the precipitate in the
reaction. (c) Write complete and net ionic equations for the reaction that
occurs when the two solutions are mixed. (d) From the calorimetric data,
calculate \(\Delta H\) for the reaction that occurs on mixing. Assume that the
calorimeter absorbs only a negligible quantity of heat, that the total volume
of the solution is 100.0 \(\mathrm{mL},\) and that the specific heat and density
of the solution after mixing are the same as that of pure water.