(a) What is meant by the term standard conditions with reference to enthalpy changes? (b) What is meant by the term enthalpy of formation? (c) What is meant by the term standard enthalpy of formation?

Short Answer

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(a) The term "standard conditions with reference to enthalpy changes" means the measure of heat gained or released during a chemical reaction when the reaction takes place at 25°C (298 K) and 100 kPa (1 atm). (b) Enthalpy of formation, ΔHf, is the change in enthalpy during the formation of one mole of a compound from its constituent elements in their standard states. (c) Standard enthalpy of formation, ΔHf°, is the change in enthalpy during the formation of one mole of a compound from its constituent elements in their standard states, but under standard conditions (temperature of 298 K and pressure of 100 kPa).

Step by step solution

01

(a) Standard Conditions and Enthalpy Change

To understand the term "standard conditions with reference to enthalpy changes," let's break it down into two parts: standard conditions and enthalpy changes. Standard conditions refers to the set of conditions under which measurements are made to enable comparability between different experiments. For enthalpy changes, the standard conditions typically refer to: - A temperature of 25°C (298 K) - A pressure of 100 kPa (1 atm) Enthalpy change, ΔH, represents the heat gained or released during a chemical reaction at constant pressure. Now, combining both concepts, "standard conditions with reference to enthalpy changes" means the measure of heat gained or released during a chemical reaction when the reaction takes place at 25°C and 100 kPa.
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(b) Enthalpy of Formation

Enthalpy of formation, ΔHf, is defined as the change in enthalpy during the formation of one mole of a compound from its constituent elements in their standard states. In other words, it's the heat released or absorbed when a compound is formed from its elements, either as they exist in nature or in some other defined state.
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(c) Standard Enthalpy of Formation

Standard enthalpy of formation, ΔHf°, is the change in enthalpy during the formation of one mole of a compound from its constituent elements in their standard states, but under standard conditions (temperature of 298 K and pressure of 100 kPa). It provides a useful point of reference for comparing the relative stability of different compounds and helps in predicting the enthalpy changes for different reactions.

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