Chapter 5: Problem 67
(a) What is meant by the term standard conditions with reference to enthalpy changes? (b) What is meant by the term enthalpy of formation? (c) What is meant by the term standard enthalpy of formation?
Chapter 5: Problem 67
(a) What is meant by the term standard conditions with reference to enthalpy changes? (b) What is meant by the term enthalpy of formation? (c) What is meant by the term standard enthalpy of formation?
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Get started for freeSuppose that the gas-phase reaction \(2 \mathrm{NO}(g)+\mathrm{O}_{2}(g) \longrightarrow\) \(2 \mathrm{NO}_{2}(g)\) were carried out in a constant-volume container at constant temperature. Would the measured heat change represent \(\Delta H\) or \(\Delta E ?\) If there is a difference, which quantity is larger for this reaction? Explain.
The standard enthalpies of formation of gaseous propyne \(\left(\mathrm{C}_{3} \mathrm{H}_{4}\right),\) propylene \(\left(\mathrm{C}_{3} \mathrm{H}_{6}\right),\) and propane \(\left(\mathrm{C}_{3} \mathrm{H}_{8}\right)\) are +185.4 \(+20.4,\) and \(-103.8 \mathrm{~kJ} / \mathrm{mol}\), respectively. (a) Calculate the heat evolved per mole on combustion of each substance to yield \(\mathrm{CO}_{2}(g)\) and \(\mathrm{H}_{2} \mathrm{O}(g)\) (b) Calculate the heat evolved on combustion of \(1 \mathrm{~kg}\) of each substance. (c) Which is the most efficient fuel in terms of heat evolved per unit mass?
The decomposition of slaked lime, \(\mathrm{Ca}(\mathrm{OH})_{2}(s),\) into lime, \(\mathrm{CaO}(s),\) and \(\mathrm{H}_{2} \mathrm{O}(g)\) at constant pressure requires the addition of \(109 \mathrm{~kJ}\) of heat per mole of \(\mathrm{Ca}(\mathrm{OH})_{2}\). (a) Write a balanced thermochemical equation for the reaction. (b) Draw an enthalpy diagram for the reaction.
You are given \(\Delta H\) for a process that occurs at constant pressure. What additional information do you need to determine \(\Delta E\) for the process?
(a) A serving of a particular ready-to-serve chicken noodle soup contains \(2.5 \mathrm{~g}\) fat, \(14 \mathrm{~g}\) carbohydrate, and \(7 \mathrm{~g}\) protein. Estimate the number of Calories in a serving. (b) According to its nutrition label, the same soup also contains \(690 \mathrm{mg}\) of sodium. Do you think the sodium contributes to the caloric content of the soup?
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