Under constant-volume conditions, the heat of combustion of benzoic acid
\(\left(\mathrm{C}_{6} \mathrm{H}_{5} \mathrm{COOH}\right)\) is \(26.38
\mathrm{~kJ} / \mathrm{g}\). A 2.760 -g sample of benzoic acid is burned in a
bomb calorimeter. The temperature of the calorimeter increases from
\(21.60^{\circ} \mathrm{C}\) to \(29.93^{\circ} \mathrm{C}\). (a) What is the
total heat capacity of the calorimeter? (b) \(\mathrm{A}\) 1.440-g sample of a
new organic substance is combusted in the same calorimeter. The temperature of
the calorimeter increases from \(22.14^{\circ} \mathrm{C}\) to \(27.09^{\circ}
\mathrm{C}\). What is the heat of combustion per gram of the new substance? (c)
Suppose that in changing samples, a portion of the water in the calorimeter
were lost. In what way, if any, would this change the heat capacity of the
calorimeter?