Find three examples of ions in the periodic table that have an electron configuration of \(n d^{8}(n=3,4,5 \ldots) .\)

Short Answer

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Three examples of ions in the periodic table that have an electron configuration of \(n d^{8}(n=3,4,5 \ldots)\) are: 1. \(Pd^{2+}\) with a \(4 d^8\) electron configuration. 2. \(Pt^{2+}\) with a \(5 d^8\) electron configuration. 3. \(Ir^{-}\) with a \(5 d^8\) electron configuration.

Step by step solution

01

Recall the periodic table structure and electron configurations

In order to solve this exercise, we need to recall the structure of the periodic table, and the rules for writing electron configurations. The periodic table is divided into groups (columns) and periods (rows). The elements in the same group have the same number of valence electrons. The electron configuration determines the distribution of electrons in the atomic orbitals. The electron configuration follows Aufbau principle, Hund's rule and Pauli's exclusion principle, and can be written in the form of \(\text{Principal Quantum Number} (\text{Orbital})^{\text{Number of Electrons}}\), such as "1s²2s²2p²".
02

Find the elements with the corresponding electron configurations

Now we need to find the elements with electron configurations of \(n d^{8}(n=3,4,5 \ldots)\). In general, these configurations are common in the transition metals which are located in the d-block of the periodic table.
03

Determine the three ions with \(nd^8\) electron configuration

To obtain ions with given electron configurations, we need to focus on comparing the general electron configuration of their neutral state and the following given configurations: 1. \(3 d^{8}\) 2. \(4 d^{8}\) 3. \(5 d^{8}\) As our first example, consider the neutral palladium (Pd) atom, which has an electron configuration of [Kr] \(4 d^{10} 5 s^0\). If we remove two electrons from the 4d orbital, we get the \(Pd^{2+}\) ion with an electron configuration of [Kr] \(4 d^8\). For the second example, let's look at the neutral platinum (Pt) atom. It has an electron configuration of [Xe] \(4 f^{14} 5 d^{9} 6 s^1\). If we remove an electron from the 5d orbital and another from the 6s orbital, we get the \(Pt^{2+}\) ion with an electron configuration of [Xe] \(4 f^{14} 5 d^{8}\). For the third example, let's take the neutral iridium (Ir) atom. Its electron configuration is [Xe] \(4 f^{14} 5 d^{7} 6 s^2\). If we add an electron to the 5d orbital, we get the \(Ir^{-}\) ion with an electron configuration of [Xe] \(4 f^{14} 5 d^{8}\). These three ions are examples for the given electron configurations: \(Pd^{2+}\) with a \(4 d^8\) electron configuration, \(Pt^{2+}\) with a \(5 d^8\) electron configuration, and \(Ir^{-}\) with a \(5 d^8\) electron configuration.

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Most popular questions from this chapter

When magnesium metal is burned in air (Figure 3.6 ), two products are produced. One is magnesium oxide, \(\mathrm{MgO}\). The other is the product of the reaction of \(\mathrm{Mg}\) with molecular nitrogen, magnesium nitride. When water is added to magnesium nitride, it reacts to form magnesium oxide and ammonia gas. (a) Based on the charge of the nitride ion (Table 2.5 ), predict the formula of magnesium nitride. (b) Write a balanced equation for the reaction of magnesium nitride with water. What is the driving force for this reaction? (c) In an experiment a piece of magnesium ribbon is burned in air in a crucible. The mass of the mixture of \(\mathrm{MgO}\) and magnesium nitride after burning is \(0.470 \mathrm{~g}\). Water is added to the crucible, further reaction occurs, and the crucible is heated to dryness until the final product is \(0.486 \mathrm{~g}\) of \(\mathrm{MgO}\). What was the mass percentage of magnesium nitride in the mixture obtained after the initial burning? (d) Magnesium nitride can also be formed by reaction of the metal with ammonia at high temperature. Write a balanced equation for this reaction. If a 6.3 -g Mg ribbon reacts with \(2.57 \mathrm{~g} \mathrm{NH}_{3}(g)\) and the reaction goes to completion, which component is the limiting reactant? What mass of \(\mathrm{H}_{2}(g)\) is formed in the reaction? (e) The standard enthalpy of formation of solid magnesium nitride is \(-461.08 \mathrm{~kJ} / \mathrm{mol} .\) Calculate the standard enthalpy change for the reaction between magnesium metal and ammonia gas.

Consider the isoelectronic ions \(\mathrm{F}^{-}\) and \(\mathrm{Na}^{+}\). (a) Which ion is smaller? (b) Using Equation 7.1 and assuming that core electrons contribute 1.00 and valence electrons contribute 0.00 to the screening constant, \(S,\) calculate \(Z_{\text {eff }}\) for the \(2 p\) electrons in both ions. (c) Repeat this calculation using Slater's rules to estimate the screening constant, \(S\). (d) For isoelectronic ions, how are effective nuclear charge and ionic radius related?

(a) Why does Li have a larger first ionization energy than Na? (b) The difference between the third and fourth ionization energies of scandium is much larger than the difference between the third and fourth ionization energies of titanium. Why? (c) Why does Li have a much larger second ionization energy than Be?

Elements in group \(7 \mathrm{~A}\) in the periodic table are the halogens; elements in group \(6 \mathrm{~A}\) are called the chalcogens. (a) What is the most common oxidation state of the chalcogens compared to the halogens? Can you suggest an explanation for the difference? (b) For each of the following periodic properties, state whether the halogens or the chalcogens have larger values: atomic radii; ionic radii of the most common oxidation state; first ionization energy; second ionization energy.

How do the sizes of atoms change as we move (a) from left to right across a row in the periodic table, (b) from top to bottom in a group in the periodic table? (c) Arrange the following atoms in order of increasing atomic radius: \(\mathrm{O}, \mathrm{Si}, \mathrm{I}, \mathrm{Ge} .\)

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