Chapter 7: Problem 52
If the electron affinity for an element is a negative number, does it mean that the anion of the element is more stable than the neutral atom? Explain.
Chapter 7: Problem 52
If the electron affinity for an element is a negative number, does it mean that the anion of the element is more stable than the neutral atom? Explain.
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Get started for freeNote from the following table that the increase in atomic radius in moving from \(\mathrm{Zr}\) to \(\mathrm{Hf}\) is smaller than in moving from \(\mathrm{Y}\) to La. Suggest an explanation for this effect. \begin{tabular}{llll} \hline \multicolumn{3}{l} { Atomic Radii \((\AA)\)} \\ \hline Sc & 1.44 & \(\mathrm{Ti}\) & 1.36 \\ \(\mathrm{Y}\) & 1.62 & \(\mathrm{Zr}\) & 1.48 \\ \(\mathrm{La}\) & 1.69 & \(\mathrm{Hf}\) & 1.50 \end{tabular}
Write a balanced equation for the reaction that occurs in each of the following cases: (a) Ozone decomposes to dioxygen. (b) Xenon reacts with fluorine. (Write three different equations.) (c) Sulfur reacts with hydrogen gas. (d) Fluorine reacts with water.
Moseley established the concept of atomic number by studying X-rays emitted by the elements. The X-rays emitted by some of the elements have the following wavelengths: $$ \begin{array}{ll} \hline \text { Element } & \text { Wavelength }(\AA) \\\ \hline \mathrm{Ne} & 14.610 \\ \mathrm{Ca} & 3.358 \\ \mathrm{Zn} & 1.435 \\\ \mathrm{Zr} & 0.786 \\ \mathrm{Sn} & 0.491 \\ \hline \end{array} $$
(a) One of the alkali metals reacts with oxygen to form a solid white substance. When this substance is dissolved in water, the solution gives a positive test for hydrogen peroxide, \(\mathrm{H}_{2} \mathrm{O}_{2}\). When the solution is tested in a burner flame, a lilac-purple flame is produced. What is the likely identity of the metal? (b) Write a balanced chemical equation for reaction of the white substance with water.
Predict whether each of the following oxides is ionic or molecular: \(\mathrm{SnO}_{2}, \mathrm{Al}_{2} \mathrm{O}_{3}, \mathrm{CO}_{2}, \mathrm{Li}_{2} \mathrm{O}, \mathrm{Fe}_{2} \mathrm{O}_{3}, \mathrm{H}_{2} \mathrm{O} .\) Explain the reasons for your choices.
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