Chapter 8: Problem 32
Which of these elements are unlikely to form covalent bonds: \(\mathrm{S}, \mathrm{H}, \mathrm{K}, \mathrm{Ar},\) Si? Explain your choices.
Chapter 8: Problem 32
Which of these elements are unlikely to form covalent bonds: \(\mathrm{S}, \mathrm{H}, \mathrm{K}, \mathrm{Ar},\) Si? Explain your choices.
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Get started for freeUse Table 8.4 to estimate the enthalpy change for each of the following reactions: (a) \(\mathrm{H}_{2} \mathrm{C}=\mathrm{O}(g)+\mathrm{HCl}(g) \longrightarrow \mathrm{H}_{3} \mathrm{C}-\mathrm{O}-\mathrm{Cl}(g)\) (b) \(\mathrm{H}_{2} \mathrm{O}_{2}(g)+2 \mathrm{CO}(g) \longrightarrow \mathrm{H}_{2}(g)+2 \mathrm{CO}_{2}(g)\) (c) \(3 \mathrm{H}_{2} \mathrm{C}=\mathrm{CH}_{2}(g) \longrightarrow \mathrm{C}_{6} \mathrm{H}_{12}(g)\) (the six carbon atoms form a six-membered ring with two \(\mathrm{H}\) atoms on each \(\mathrm{C}\) atom \()\)
Predict the ordering of the \(\mathrm{C}-\mathrm{O}\) bond lengths in \(\mathrm{CO}, \mathrm{CO}_{2}\), and \(\mathrm{CO}_{3}^{2-}\).
Which ionic compound is expected to form from combining the following pairs of elements: (a) barium and fluorine, (b) cesium and chlorine, (c) lithium and nitrogen, (d) aluminum and oxygen?
(a) Write the electron configuration for the element titanium, Ti. How many valence electrons does this atom possess? (b) Hafnium, Hf, is also found in group \(4 \mathrm{~B}\). Write the electron configuration for Hf. (c) Ti and Hf behave as though they possess the same number of valence electrons. Which of the subshells in the electron configuration of Hf behave as valence orbitals? Which behave as core orbitals?
In the vapor phase, \(\mathrm{BeCl}_{2}\) exists as a discrete molecule. (a) Draw the Lewis structure of this molecule, using onlysingle bonds. Does this Lewis structure satisfy the octet rule? (b) What other resonance structures are possible that satisfy the octet rule? (c) On the basis of the formal charges, which Lewis structure is expected to be dominant for \(\mathrm{BeCl}_{2} ?\)
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