(a) State the octet rule. (b) Does the octet rule apply to ionic as well as to covalent compounds? Explain using examples as appropriate.

Short Answer

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(a) The octet rule states that atoms tend to combine in such a way that they each have eight electrons in their outermost electron shell, resulting in a more stable electron configuration. (b) Yes, the octet rule generally applies to both ionic and covalent compounds, though there are some exceptions. In ionic compounds, such as sodium chloride (NaCl), metal atoms transfer electrons to non-metal atoms, forming cations and anions that have complete octets. In covalent compounds, like water (H2O), atoms share electrons to achieve stable electron configurations with eight valence electrons (octet rule) or two valence electrons (duet rule, as in the case of hydrogen). However, elements in the third period and beyond may exceed the octet due to the presence of d-orbitals, and some elements like hydrogen follow the duet rule.

Step by step solution

01

(a) State the octet rule.

(In chemistry, the octet rule states that atoms tend to combine in such a way that they each have eight electrons in their outermost electron shell, also known as the valence shell, resulting in a more stable electron configuration. This rule is based on the fact that a complete set of eight electrons provides the most stable electron configuration for an atom.)
02

(b) Does the octet rule apply to ionic as well as covalent compounds?

(Yes, the octet rule generally applies to both ionic and covalent compounds, though there are some exceptions. An ionic compound forms when a metal atom transfers one or more of its electrons to a non-metal atom, whereas a covalent compound forms when two non-metal atoms share one or more pairs of electrons. In both cases, the atoms involved form bonds to reach a stable electron configuration with eight electrons in their outermost shell. However, some elements, particularly those in the third period and onward in the periodic table, may exceed the octet due to the presence of d-orbitals. Additionally, some elements like hydrogen obey the "duet rule," forming stable compounds with only two electrons in their outermost shell.)
03

Examples of the octet rule in ionic compounds

(In ionic compounds, the transfer of electrons between atoms results in the formation of positively charged cations and negatively charged anions. For example, consider the formation of sodium chloride (NaCl). Sodium (Na) has one electron in its outermost shell and needs to lose one to achieve stable configuration akin to a noble gas (like Neon), while chlorine (Cl) has seven electrons in its valence shell and requires one additional electron to achieve an octet. Sodium transfers its single valence electron to chlorine, becoming a positively charged Na^+ ion, and chlorine becomes a negatively charged Cl^- ion with a filled octet. The positively charged sodium ion and negatively charged chloride ion form an ionic bond, completing their octets.)
04

Examples of the octet rule in covalent compounds

(In covalent compounds, atoms share electrons to achieve a stable electron configuration with eight electrons in their valence shell. A common example is water (H2O). Oxygen has six valence electrons, requiring two more to achieve an octet. Hydrogen, following the duet rule, has one electron and needs one more to complete its outermost shell. Each hydrogen atom shares its electron with oxygen, forming two covalent bonds in a water molecule. This electron sharing allows every atom in the molecule to achieve stable electron configurations, with oxygen following the octet rule and both hydrogen atoms following the duet rule.)

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Most popular questions from this chapter

In the following pairs of binary compounds determine which one is a molecular substance and which one is an ionic substance. Use the appropriate naming convention (for ionic or molecular substances) to assign a name to each compound: (a) \(\mathrm{SiF}_{4}\) and \(\mathrm{LaF}_{3}\), (b) \(\mathrm{FeCl}_{2}\) and \(\mathrm{ReCl}_{6}\) (c) \(\mathrm{PbCl}_{4}\) and \(\mathrm{RbCl}\).

Write the electron configuration for silicon. Identify the valence electrons in this configuration and the nonvalence electrons. From the standpoint of chemical reactivity, what is the important difference between them?

For each of the following molecules or ions of sulfur and oxygen, write a single Lewis structure that obeys the octet rule, and calculate the oxidation numbers and formal charges on all the atoms: \((\mathrm{a}) \mathrm{SO}_{2},(\mathrm{~b}) \mathrm{SO}_{3},(\mathrm{c}) \mathrm{SO}_{3}{ }^{2-},\) (d) Arrange these mol- ecules/ions in order of increasing \(\mathrm{S}-\mathrm{O}\) bond distance.

Illustrated are four ions \(-\mathrm{A}, \mathrm{B}, \mathrm{X},\) and \(\mathrm{Y}-\) showing their relative ionic radii. The ions shown in red carry positive charges: \(2+\) charge for \(A\) and a \(1+\) charge for \(B\). Ions shown in blue carry negative charges: a 1 - charge for \(\mathrm{X}\) and a 2 - charge for \(\mathrm{Y}\). (a) Which combinations of these ions produce ionic compounds where there is a 1:1 ratio of cations and anions? (b) Among the combinations in part (a), which leads to the ionic compound having the largest lattice energy? (c) Which combination of ions leads to the ionic compound having the smallest lattice energy? [Section 8.2\(]\)

Based on Lewis structures, predict the ordering of \(\mathrm{N}-\mathrm{O}\) bond lengths in \(\mathrm{NO}^{+}, \mathrm{NO}_{2}^{-},\) and \(\mathrm{NO}_{3}^{-}\).

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