Chapter 8: Problem 59
(a) State the octet rule. (b) Does the octet rule apply to ionic as well as to covalent compounds? Explain using examples as appropriate.
Chapter 8: Problem 59
(a) State the octet rule. (b) Does the octet rule apply to ionic as well as to covalent compounds? Explain using examples as appropriate.
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Get started for freeIn the following pairs of binary compounds determine which one is a molecular substance and which one is an ionic substance. Use the appropriate naming convention (for ionic or molecular substances) to assign a name to each compound: (a) \(\mathrm{SiF}_{4}\) and \(\mathrm{LaF}_{3}\), (b) \(\mathrm{FeCl}_{2}\) and \(\mathrm{ReCl}_{6}\) (c) \(\mathrm{PbCl}_{4}\) and \(\mathrm{RbCl}\).
Write the electron configuration for silicon. Identify the valence electrons in this configuration and the nonvalence electrons. From the standpoint of chemical reactivity, what is the important difference between them?
For each of the following molecules or ions of sulfur and oxygen, write a single Lewis structure that obeys the octet rule, and calculate the oxidation numbers and formal charges on all the atoms: \((\mathrm{a}) \mathrm{SO}_{2},(\mathrm{~b}) \mathrm{SO}_{3},(\mathrm{c}) \mathrm{SO}_{3}{ }^{2-},\) (d) Arrange these mol- ecules/ions in order of increasing \(\mathrm{S}-\mathrm{O}\) bond distance.
Illustrated are four ions \(-\mathrm{A}, \mathrm{B}, \mathrm{X},\) and \(\mathrm{Y}-\) showing their relative ionic radii. The ions shown in red carry positive charges: \(2+\) charge for \(A\) and a \(1+\) charge for \(B\). Ions shown in blue carry negative charges: a 1 - charge for \(\mathrm{X}\) and a 2 - charge for \(\mathrm{Y}\). (a) Which combinations of these ions produce ionic compounds where there is a 1:1 ratio of cations and anions? (b) Among the combinations in part (a), which leads to the ionic compound having the largest lattice energy? (c) Which combination of ions leads to the ionic compound having the smallest lattice energy? [Section 8.2\(]\)
Based on Lewis structures, predict the ordering of \(\mathrm{N}-\mathrm{O}\) bond lengths in \(\mathrm{NO}^{+}, \mathrm{NO}_{2}^{-},\) and \(\mathrm{NO}_{3}^{-}\).
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