Chapter 8: Problem 77
How many elements in the periodic table are represented by a Lewis symbol with a single dot? Are all these elements in the same group? Explain.
Chapter 8: Problem 77
How many elements in the periodic table are represented by a Lewis symbol with a single dot? Are all these elements in the same group? Explain.
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Get started for freeDraw the Lewis structures for each of the following molecules or ions. Which do not obey the octet rule? (a) \(\mathrm{NO},\) (b) \(\mathrm{BF}_{3}\), (c) \(\mathrm{ICl}_{2}^{-}\) (d) \(\mathrm{OPBr}_{3}\) (the \(\mathrm{P}\) is the central atom), (e) XeF 4 .
Explain the following trends in lattice energy: (a) \(\mathrm{NaCl}>\mathrm{RbBr}>\mathrm{CsBr} ;\) (b) \(\mathrm{BaO}>\mathrm{KF}\) (c) \(\mathrm{SrO}>\mathrm{SrCl}_{2}\)
Using Lewis symbols, diagram the reaction between magnesium and oxygen atoms to give the ionic substance \(\mathrm{MgO}\).
A common form of elemental phosphorus is the tetrahedral \(\mathrm{P}_{4}\) molecule, where all four phosphorus atoms are equivalent: At room temperature phosphorus is a solid. (a) Do you think there are any unshared pairs of electrons in the \(\mathrm{P}_{4}\) molecule? (b) How many \(\mathrm{P}-\mathrm{P}\) bonds are there in the molecule? (c) Can you draw a Lewis structure for a linear \(\mathrm{P}_{4}\) molecule that satisfies the octet rule? (d) Using formal charges, what can you say about the stability of the linear molecule versus that of the tetrahedral molecule?
For elements in the third row of the periodic table and beyond, the octet rule is often not obeyed. What factors are usually cited to explain this fact?
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