Chapter 9: Problem 23
What is the difference between the electron-domain geometry and the molecular geometry of a molecule? Use the water molecule as an example in your discussion. Why do we need to make this distinction?
Chapter 9: Problem 23
What is the difference between the electron-domain geometry and the molecular geometry of a molecule? Use the water molecule as an example in your discussion. Why do we need to make this distinction?
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Get started for free(a) The \(\mathrm{PH}_{3}\) molecule is polar. Does this offer experimental proof that the molecule cannot be planar? Explain. (b) It turns out that ozone, \(\mathrm{O}_{3}\), has a small dipole moment. How is this possible, given that all the atoms are the same?
(a) Starting with the orbital diagram of a sulfur atom, describe the steps needed to construct hybrid orbitals appropriate to describe the bonding in \(\mathrm{SF}_{2}\). (b) What is the name given to the hybrid orbitals constructed in (a)? (c) Sketch the large lobes of these hybrid orbitals. (d) Would the hybridization scheme in part (a) be appropriate for \(\mathrm{SF}_{4} ?\) Explain.
Why are there no \(s p^{4}\) or \(s p^{5}\) hybrid orbitals?
(a) Draw a picture showing how two \(p\) orbitals on two different atoms can be combined to make a sigma bond. (b) Sketch a \(\pi\) bond that is constructed from \(p\) orbitals. (c) Which is generally stronger, a \(\sigma\) bond or a \(\pi\) bond? Explain. (d) Can two \(s\) orbitals combine to form a \(\pi\) bond? Explain.
(a) What does the term diamagnetism mean? (b) How does a diamagnetic substance respond to a magnetic field? (c) Which of the following ions would you expect to be diamagnetic: \(\mathrm{N}_{2}^{2-}, \mathrm{O}_{2}^{2-}, \mathrm{Be}_{2}^{2+}, \mathrm{C}_{2}^{-} ?\)
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