Chapter 9: Problem 7
The orbital diagram that follows presents the final step in the formation of hybrid orbitals by a silicon atom. What type of hybrid orbital is produced in this hybridization? [Section 9.5\(]\)
Chapter 9: Problem 7
The orbital diagram that follows presents the final step in the formation of hybrid orbitals by a silicon atom. What type of hybrid orbital is produced in this hybridization? [Section 9.5\(]\)
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Get started for freeDraw the Lewis structure for each of the following molecules or ions, and predict their electron-domain and molecular geometries: (a) \(\mathrm{AsF}_{3},\) (b) \(\mathrm{CH}_{3}^{+},\) (c) \(\mathrm{BrF}_{3},\) (d) \(\mathrm{ClO}_{3}^{-},\) (e) \(\mathrm{XeF}_{2}\), (f) \(\mathrm{BrO}_{2}^{-}\).
In the series \(\mathrm{SiF}_{4}, \mathrm{PF}_{3},\) and \(\mathrm{SF}_{2},\) estimate the \(\mathrm{F}-\mathrm{X}-\mathrm{F}\) bond angle in each case and explain your rationale. [Section 9.2\(]\)
In which of these molecules or ions does the presence of nonbonding electron pairs produce an effect on molecular shape, assuming they are all in the gaseous state? (a) \(\mathrm{SiH}_{4}\) (b) \(\mathrm{PF}_{3},\) (c) \(\mathrm{HBr}\), (d) \(\mathrm{HCN},\) (e) \(\mathrm{SO}_{2}\)
Describe the bond angles to be found in each of the following molecular structures: (a) planar trigonal, (b) tetrahedral, (c) octahedral, (d) linear.
Draw sketches illustrating the overlap between the following orbitals on two atoms: (a) the \(2 s\) orbital on each atom, (b) the \(2 p_{z}\) orbital on each atom (assume both atoms are on the \(z\) -axis), \((\mathrm{c})\) the \(2 s\) orbital on one atom and the \(2 p_{z}\) orbital on the other atom.
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