At constant pressure, the mean free path \((\lambda)\) of a gas molecule is directly proportional to temperature. At constant temperature, \(\lambda\) is inversely proportional to pressure. If you compare two different gas molecules at the same temperature and pressure, \(\lambda\) is inversely proportional to the square of the diameter of the gas molecules. Put these facts together to create a formula for the mean free path of a gas molecule with a proportionality constant (call it \(R_{\text { mfp }}\) , like the ideal-gas constant) and define units for \(R_{\operatorname{mfp}}\) .

Short Answer

Expert verified
The formula for the mean free path of a gas molecule, considering the given relationships, is: \[ \lambda = R_{\text { mfp }} \frac{T}{Pd^2} \] where \(\lambda\) is the mean free path, \(R_{\text { mfp }}\) is the proportionality constant with the unit \(\frac{\text{Pa}\cdot\text{m}^2}{\text{K}}\), \(T\) is the temperature in Kelvin, \(P\) is the pressure in pascals, and \(d\) is the diameter of the gas molecules in meters.

Step by step solution

01

Relationship 1: Mean free path and temperature

According to the first relationship, the mean free path of a gas molecule is directly proportional to temperature at constant pressure. Mathematically, this can be represented as: \[ \lambda \propto T \]
02

Relationship 2: Mean free path and pressure

According to the second relationship, the mean free path of a gas molecule is inversely proportional to pressure at constant temperature. Mathematically, this can be represented as: \[ \lambda \propto \frac{1}{P} \]
03

Relationship 3: Mean free path and diameter

According to the third relationship, the mean free path of a gas molecule is inversely proportional to the square of the diameter of the gas molecules at the same temperature and pressure. Let's represent the diameter of the gas molecules as \(d\). Therefore, we have: \[ \lambda \propto \frac{1}{d^2} \]
04

Combining the relationships

To combine these three relationships into a single formula, we will multiply the proportionalities together: \[ \lambda \propto \frac{T}{Pd^2} \]
05

Introducing proportionality constant \(R_{\text{mfp}}\)

To convert the proportionality into an equation, we need to introduce a proportionality constant \(R_{\text { mfp }}\): \[ \lambda = R_{\text { mfp }} \frac{T}{Pd^2} \]
06

Units of \(R_{\text{mfp}}\)

Now let's analyze the units of \(R_{\text { mfp }}\) to get the final answer. We will use SI units: - Mean free path \(\lambda\) has the unit of length: meters (m). - Temperature \(T\) is measured in Kelvin (K). - Pressure \(P\) is measured in pascals (Pa). - Diameter \(d\) is measured in meters (m). Thus, the units for \(R_{\text { mfp }}\) can be written as: \[ \text{meters} \cdot \frac{\text{pascals} \cdot \text{meters}^2}{\text{Kelvin}} = \frac{\text{Pa} \cdot \text{m}^2}{\text{K}} \] So, the formula for the mean free path of a gas molecule is: \[ \lambda = R_{\text { mfp }} \frac{T}{Pd^2} \] where \(R_{\text { mfp }}\) is the proportionality constant with the unit \(\frac{\text{Pa}\cdot\text{m}^2}{\text{K}}\).

Unlock Step-by-Step Solutions & Ace Your Exams!

  • Full Textbook Solutions

    Get detailed explanations and key concepts

  • Unlimited Al creation

    Al flashcards, explanations, exams and more...

  • Ads-free access

    To over 500 millions flashcards

  • Money-back guarantee

    We refund you if you fail your exam.

Over 30 million students worldwide already upgrade their learning with Vaia!

One App. One Place for Learning.

All the tools & learning materials you need for study success - in one app.

Get started for free

Most popular questions from this chapter

Mars has an average atmospheric pressure of 0.007 atm. Would it be easier or harder to drink from a straw on Mars than on Earth? Explain. [Section 10.2]

A piece of dry ice (solid carbon dioxide) with a mass of 5.50 \(\mathrm{g}\) is placed in a 10.0 -L vessel that already contains air at 705 torr and \(24^{\circ} \mathrm{C}\) . After the carbon dioxide has totally sublimed, what is the partial pressure of the resultant CO\(_{2}\) gas, and the total pressure in the container at \(24^{\circ} \mathrm{C} ?\)

Which of the following statements best explains why nitrogen gas at STP is less dense than Xe gas at STP? \begin{equation}\begin{array}{l}{\text { (a) Because Xe is a noble gas, there is less tendency for the Xe }} \\ {\text { atoms to repel one another, so they pack more densely in }} \\ {\text { the gaseous state. }} \\ {\text { (b) Xe atoms have a higher mass than } \mathrm{N}_{2} \text { molecules. Because }} \\ {\text { both gases at STP have the same number of molecules per }} \\ {\text { unit volume, the Xe gas must be denser. }}\\\\{\text { (c) The Xe atoms are larger than } \mathrm{N}_{2} \text { molecules and thus take }} \\ {\text { up a larger fraction of the space occupied by the gas. }} \\\ {\text { (d) Because the Xe atoms are much more massive than the }} \\\ {\mathrm{N}_{2} \text { molecules, they move more slowly and thus exert }} \\\ {\text { less upward force on the gas container and make the gas }} \\ {\text { appear denser. }}\end{array}\end{equation}

An herbicide is found to contain only \(\mathrm{C}, \mathrm{H}, \mathrm{N},\) and Cl. The complete combustion of a 100.0 -mg sample of the herbicide in excess oxygen produces 83.16 \(\mathrm{mL}\) of \(\mathrm{CO}_{2}\) and 73.30 \(\mathrm{mL}\) of \(\mathrm{H}_{2} \mathrm{O}\) vapor expressed at STP. A separate analysis shows that the sample also contains 16.44 \(\mathrm{mg}\) of Cl. (a) Determine the percentage of the composition of the substance. ( b) Calculate its empirical formula. (c) What other information would you need to know about this compound to calculate its true molecular formula?

(a) If the pressure exerted by ozone, \(\mathrm{O}_{3},\) in the stratosphere is \(3.0 \times 10^{-3}\) atm and the temperature is 250 \(\mathrm{K}\) , how many ozone molecules are in a liter? (b) Carbon dioxide makes up approximately 0.04\(\%\) of Earth's atmosphere. If you collect a \(2.0-\mathrm{L}\) sample from the atmosphere at sea level \((1.00 \mathrm{atm})\) on a warm day \(\left(27^{\circ} \mathrm{C}\right),\) how many \(\mathrm{CO}_{2}\) molecules are in your sample?

See all solutions

Recommended explanations on Chemistry Textbooks

View all explanations

What do you think about this solution?

We value your feedback to improve our textbook solutions.

Study anywhere. Anytime. Across all devices.

Sign-up for free