Chapter 12: Problem 107
Introduction of carbon into a metallic lattice generally results in a harder, less ductile substance with lower electrical and thermal conductivities. Explain why this might be so.
Chapter 12: Problem 107
Introduction of carbon into a metallic lattice generally results in a harder, less ductile substance with lower electrical and thermal conductivities. Explain why this might be so.
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Get started for freeRed light-emitting diodes are made from GaAs and GaP solid solutions, GaP \(_{x} A s_{1-x}(\) see Exercise 12.79\() .\) The original red LEDs emitted light with a wavelength of 660 nm. If we assume that the band gap varies linearly with composition between \(x=0\) and \(x=1,\) estimate the composition (the value of \(x\) ) that is used in these LEDs.
What is the minimum number of atoms that could be contained in the unit cell of an element with a body-centered cubic lattice? (a) \(1,(\mathbf{b}) 2,(\mathbf{c}) 3,(\mathbf{d}) 4,(\mathbf{e}) 5\)
The coordination number for \(\mathrm{Mg}^{2+}\) ion is usually six. Assuming this assumption holds, determine the anion coordination number in the following compounds: (a) MgS, (b) \(\mathrm{MgF}_{2},(\mathbf{c}) \mathrm{MgO}\)
Amorphous silica, \(\mathrm{SiO}_{2},\) has a density of about 2.2 \(\mathrm{g} / \mathrm{cm}^{3}\) , whereas the density of crystalline quartz, another form of \(\mathrm{SiO}_{2},\) is 2.65 \(\mathrm{g} / \mathrm{cm}^{3} .\) Which of the following statements is the best explanation for the difference in density? $$ \begin{array}{l}{\text { (a) Amorphous silica is a network-covalent solid, but quartz }} \\ {\text { is metallic. }} \\ {\text { (b) Amorphous silica crystallizes in a primitive cubic lattice. }} \\ {\text { (c) Quartz is harder than amorphous silica. }}\end{array} $$ $$ \begin{array}{l}{\text { (d) Quartz must have a larger unit cell than amorphous }} \\ {\text { silica. }}\end{array} $$ $$ \begin{array}{l}{\text { (e) The atoms in amorphous silica do not pack as efficiently }} \\ {\text { in three dimensions as compared to the atoms in quartz. }}\end{array} $$
Cadmium telluride is an important material for solar cells. (a) What is the band gap of CdTe? (b) What wavelength of light would a photon of this energy correspond to? (c) Draw a vertical line at this wavelength in the figure shown in Exercise \(12.75,\) which shows the light output of the sun as a function of wavelength. (d) With respect to silicon, does CdTe absorb a larger or smaller portion of the solar spectrum?
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