Chapter 12: Problem 23
Imagine the primitive cubic lattice. Now imagine grabbing the top of it and stretching it straight up. All angles remain \(90^{\circ} .\) What kind of primitive lattice have you made?
Chapter 12: Problem 23
Imagine the primitive cubic lattice. Now imagine grabbing the top of it and stretching it straight up. All angles remain \(90^{\circ} .\) What kind of primitive lattice have you made?
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Get started for freeIn their study of X-ray diffraction, William and Lawrence Bragg determined that the relationship among the wavelength of the radiation \((\lambda),\) the angle at which the raveation is diffracted \((\theta),\) and the distance between planes of atoms in the crystal that cause the diffraction \((d)\) is given by \(n \lambda=2 d \sin \theta . X\) rays from a copper \(X\) -ray tube that have a wavelength of 1.54\(\hat{\mathrm{A}}\) are diffracted at an angle of 14.22 degrees by crystalline silicon. Using the Bragg equation, calculate the distance between the planes of atoms responsible for diffraction in this crystal, assuming \(n=1\) (first-order diffraction).
Imagine that you have a metal bar sitting half in the sun and half in the dark. On a sunny day, the part of the metal that has been sitting in the sun feels hot. If you touch the part of the metal bar that has been sitting in the dark, will it feel hot or cold? Justify your answer in terms of thermal conductivity.
The coordination number for \(\mathrm{Mg}^{2+}\) ion is usually six. Assuming this assumption holds, determine the anion coordination number in the following compounds: (a) MgS, (b) \(\mathrm{MgF}_{2},(\mathbf{c}) \mathrm{MgO}\)
Silicon is the fundamental component of integrated circuits. Si has the same structure as diamond. (a) Is Si a molecular, metallic, ionic, or covalent- network solid? (b) Silicon readily reacts to form silicon dioxide, \(\mathrm{SiO}_{2}\) , which is quite hard and is insoluble in water. Is \(\mathrm{SiO}_{2}\) most likely a molecular, metallic, ionic, or covalent- network solid?
Indicate whether this statement is true or false: If you want a semiconductor that emits blue light, you could either use a material that has a band gap corresponding to the energy of a blue photon or you could use a material that has a smaller band gap but make an appropriately sized nanoparticle of the same material.
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