Chapter 12: Problem 27
What is the minimum number of atoms that could be contained in the unit cell of an element with a body-centered cubic lattice? (a) \(1,(\mathbf{b}) 2,(\mathbf{c}) 3,(\mathbf{d}) 4,(\mathbf{e}) 5\)
Chapter 12: Problem 27
What is the minimum number of atoms that could be contained in the unit cell of an element with a body-centered cubic lattice? (a) \(1,(\mathbf{b}) 2,(\mathbf{c}) 3,(\mathbf{d}) 4,(\mathbf{e}) 5\)
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Get started for freeImagine the primitive cubic lattice. Now imagine grabbing the top of it and stretching it straight up. All angles remain \(90^{\circ} .\) What kind of primitive lattice have you made?
What kinds of attractive forces exist between particles (atoms, molecules, or ions) in (a) molecular crystals, (b) covalent-network crystals, (c) ionic crystals, (d) and metallic crystals?
The coordination number for the \(\mathrm{Al}^{3+}\) ion is typically between four and six. Use the anion coordination number to determine the \(\mathrm{Al}^{3+}\) coordination number in the following compounds: (a) AlF_ \(_{3}\) where the fluoride ions are two coordinate, (b) \(\mathrm{Al}_{2} \mathrm{O}_{3}\) where the oxygen ions are six coordinate, (c) AlN where the nitride ions are four coordinate.
An ideal quantum dot for use in TVs does not contain any cadmium due to concerns about disposal. One potential material for this purpose is InP, which adopts the zinc blende \((\mathrm{ZnS})\) structure (face-centered cubic). The unit cell edge length is 5.869 \&. (a) If the quantum dot is shaped like a cube, how many of each type of atom are there in a cubic crystal with an edge length of 3.00 \(\mathrm{nm} ? 5.00 \mathrm{nm}\) ? (b) If one of the nanoparticles in part (a) emits blue light and the other emits orange light, which color is emitted by the crystal with the 3.00 -nm edge length? With the 5.00 -nm edge length?
At room temperature and pressure RbI crystallizes with the NaCl-type structure. (a) Use ionic radii to predict the length of the cubic unit cell edge. (b) Use this value to estimate the density. (c) At high pressure the structure transforms to one with a CsCl-type structure. (c) Use ionic radii to predict the length of the cubic unit cell edge for the high-pressure form of RbI. (d) Use this value to estimate the density. How does this density compare with the density you calculated in part (b)?
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