An element crystallizes in a face-centered cubic lattice. The edge of the unit cell is 4.078\(\hat{A}\) , and the density of the crystal is 19.30 \(\mathrm{g} / \mathrm{cm}^{3} .\) Calculate the atomic weight of the element and identify the element.

Short Answer

Expert verified
In a face-centered cubic lattice, there are 4 atoms per unit cell. The volume of the unit cell is 6.797 x 10^(-23) cm³, and its mass is 1.311 x 10^(-21) g. The mass of a single atom is 3.278 x 10^(-22) g, and its atomic weight is approximately 197.38 g/mol. This atomic weight corresponds to gold (Au).

Step by step solution

01

Determine the number of atoms per unit cell for an fcc lattice

In a face-centered cubic lattice, there is one atom at each corner and one atom at the center of each face. In total, the number of atoms per unit cell is given by: AtomsPerUnitCell = 8(corner atoms) x 1/8 (atoms shared by adjacent unit cells) + 6(face atoms) x 1/2 (atoms shared by neighboring cells) AtomsPerUnitCell = 1 + 3 = 4 Therefore, in an fcc lattice, there are 4 atoms per unit cell.
02

Calculate the volume of the unit cell

We are given that the edge length of the unit cell is 4.078Å. To get the volume, we simply need to cube the edge length: Volume = (EdgeLength)³ Volume = (4.078 Å)³ Since we need the answer in cubic centimeters, we have to convert Å to cm: 4.078 Å * (1 x 10^(-8) cm) = 4.078 x 10^(-8) cm Volume = (4.078 x 10^(-8) cm)³ = 6.797 x 10^(-23) cm³
03

Calculate the mass of the unit cell

We know the density (ρ) and volume (V) of the unit cell, so we can find its mass (m) with the following equation: m = ρ x V The density of the crystal is given as 19.30 g/cm³. m = (19.30 g/cm³) x (6.797 x 10^(-23) cm³) = 1.311 x 10^(-21) g
04

Calculate the mass of a single atom

Now that we have the mass of the unit cell, we can divide the mass by the number of atoms per unit cell to find the mass of a single atom: MassOfSingleAtom = MassOfUnitCell / AtomsPerUnitCell MassOfSingleAtom = (1.311 x 10^(-21) g) / 4 = 3.278 x 10^(-22) g
05

Calculate the atomic weight and identify the element

To find the atomic weight, we first need to calculate the moles (n) of the single atom. The Avogadro's number (N_A) is 6.022 x 10^(23) atoms/mol. Therefore: n = MassOfSingleAtom x N_A n = (3.278 x 10^(-22) g) x (6.022 x 10^(23) atoms/mol) = 197.38 g/mol The atomic weight of the element is approximately 197.38 g/mol. This atomic weight corresponds to gold (Au), with a standard atomic weight of 197.0 g/mol.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Crystal Density Calculation
Crystal density is a critical concept in materials science and solid-state physics. It refers to the mass of the crystal per unit volume. The density can reveal a lot about the crystal's composition and structure. To calculate the density, one can use the formula:

\[ \rho = \frac{m}{V} \]
Where \(\rho\) is the density, \(m\) is the mass, and \(V\) is the volume. For a face-centered cubic lattice, this calculation becomes particularly interesting because of the efficient packing of atoms.

In the provided exercise, we were given the density, and our goal was to reverse-engineer the problem to find the atomic weight. However, usually, if the atomic weight is known, the density can also be calculated by manipulating the previous equation to accommodate the number of atoms in a unit cell and their individual masses.

To improve understanding of this concept, imagine filling a box with uniform spheres until no additional spheres can fit without changing the box's size. The density calculation for a crystal mirrors this idea, except instead of spheres, the box, our unit cell, is filled with atoms.
Atomic Weight Determination
The atomic weight, or atomic mass, is fundamentally important in chemistry and physics. It is a value that tells us the average mass of atoms of an element, measured in atomic mass units (amu). To find the atomic weight from the density of a crystal, we first need to calculate the mass of a single atom within the crystal lattice.

As illustrated in our problem, once we have the mass of a single atom, we can use Avogadro's number to convert this mass to atomic weight. Avogadro's number, \(6.022 \times 10^{23}\), is the number of particles in one mole of substance. The atomic weight is then represented as grams per mole (g/mol).

Understanding the route from the mass of a single atom to atomic weight involves grasping the concept of moles and Avogadro's constant. Simply put, if you know the mass of one atom and consider that one mole of any element contains the same number of atoms, you can extrapolate to find the mass of one mole of the element—its atomic weight.
Unit Cell Volume
The volume of the unit cell in a crystal lattice is the three-dimensional space that a single cell occupies. For a face-centered cubic lattice, the unit cell has a distinctive cubic shape, and hence the volume is found by cubing the edge length.

Let's recall the formula:\[ V = a^3 \]
Where \(V\) is the volume and \(a\) is the edge length of the cube. For our exercise, the unit cell's edge was given as \(4.078 \hat{A}\), or angstroms. Since volume is essentially 'how much space is taken up', understanding this calculation is like knowing how much water would fit inside a small cube-shaped container with each side of the length \(a\).

To further improve comprehension, one must remember to convert the edge length from angstroms, a common unit for atomic scales, to centimeters, which is more convenient for volume calculations in a laboratory setting. Each angstrom is one ten-billionth of a meter (\(1 \hat{A} = 1 \times 10^{-10} \) meters), a conversion necessary to align units when using density in grams per cubic centimeter (g/cm³).

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Most popular questions from this chapter

At room temperature and pressure RbI crystallizes with the NaCl-type structure. (a) Use ionic radii to predict the length of the cubic unit cell edge. (b) Use this value to estimate the density. (c) At high pressure the structure transforms to one with a CsCl-type structure. (c) Use ionic radii to predict the length of the cubic unit cell edge for the high-pressure form of RbI. (d) Use this value to estimate the density. How does this density compare with the density you calculated in part (b)?

Which type (or types) of crystalline solid is characterized by each of the following? (a) High mobility of electrons throughout the solid; (b) softness, relatively low melting point; (c) high melting point and poor electrical conductivity; ( \(\mathbf{d} )\) network of covalent bonds.

You are given a white substance that melts at \(100^{\circ} \mathrm{C}\) . The substance is soluble in water. Neither the solid nor the solution is a conductor of electricity. Which type of solid (molecular, metallic, covalent- network, or ionic) might this substance be?

Classify each of the following statements as true or false: $$ \begin{array}{l}{\text { (a) Although both molecular solids and covalent- network }} \\ {\text { solids have covalent bonds, the melting points of molec- }} \\ {\text { ular solids are much lower because their covalent bonds }} \\ {\text { are much weaker. }} \\ {\text { (b) Other factors being equal, highly symmetric molecules }} \\ {\text { tend to form solids with highly symmetric molecules }} \\ {\text { asymmetrically shaped molecules. }}\end{array} $$

Covalent bonding occurs in both molecular and covalent network solids. Which of the following statements best explains why these two kinds of solids differ so greatly in their hardness and melting points? $$ \begin{array}{l}{\text { (a) The molecules in molecular solids have stronger covalent bonding than covalent-network solids do. }} \\ {\text { (b) The molecules in molecular solids are held together by weak intermolecular interactions. }}\end{array} $$ $$ \begin{array}{l}{\text { (c) The atoms in covalent-network solids are more polarizable than those in molecular solids. }} \\ {\text { (d) Molecular solids are denser than covalent-network solids. }}\end{array} $$

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