Lauryl alcohol is obtained from coconut oil and is used to make detergents. A solution of 5.00 g of lauryl alcohol in 0.100 kg of benzene freezes at \(4.1^{\circ} \mathrm{C} .\) What is the molar mass of lauryl alcohol from this data?

Short Answer

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The molar mass of lauryl alcohol can be calculated using the freezing point depression formula. Given a mass of 5.00 g of lauryl alcohol in 0.100 kg of benzene and a freezing point depression of 4.1°C, the molality of the solution is found to be \(m = \frac{4.1\,^{\circ}\mathrm{C}}{5.12\,^{\circ}\mathrm{C\,kg/mol}} = 0.800\,\mathrm{mol/kg}\). Using the rearranged formula \(Molar\ mass\ of\ lauryl\ alcohol = \frac{Mass\ of\ lauryl\ alcohol}{(molality)(kg\ of\ solvent)}\), the molar mass of lauryl alcohol is approximately 62.5 g/mol.

Step by step solution

01

Write down the given information

We are given the following information: - Mass of lauryl alcohol: 5.00 g - Mass of benzene: 0.100 kg - Freezing point depression: 4.1°C
02

Calculate the molality of the solution

First, we need to calculate the molality (m) of the solution. Molality is defined as the number of moles of solute per kg of solvent. The formula to calculate molality is: \(m = \frac{moles\ of\ solute}{kg\ of\ solvent}\) By re-arranging this formula, we will get: \(Molar\ mass\ of\ lauryl\ alcohol = \frac{Mass\ of\ lauryl\ alcohol}{(molality)(kg\ of\ solvent)}\) We will now use the formula to calculate the molality of the solution: \(\Delta T_f = K_f \cdot m\) Where: - ΔTf is the freezing point depression (4.1°C) - Kf (benzene) is the cryoscopic constant of benzene (5.12 °C kg/mol) - m is the molality of the solution Rearranging the formula, we get: \(m = \frac{\Delta T_f}{K_f}\) Now, plug in the values: \(m = \frac{4.1\,^{\circ}\mathrm{C}}{5.12\,^{\circ}\mathrm{C\,kg/mol}} = 0.800\,\mathrm{mol/kg}\)
03

Calculate the molar mass of lauryl alcohol

Now, we will use the rearranged formula from Step 2 to calculate the molar mass of lauryl alcohol: \(Molar\ mass\ of\ lauryl\ alcohol = \frac{Mass\ of\ lauryl\ alcohol}{(molality)(kg\ of\ solvent)}\) Plugging in the values, we get: \(Molar\ mass\ of\ lauryl\ alcohol = \frac{5.00\,g}{(0.800\,\mathrm{mol/kg})(0.100\,kg)} = \frac{5.00\,g}{0.0800\,mol} = 62.5\,g/mol\) So, the molar mass of lauryl alcohol is approximately 62.5 g/mol.

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