Chapter 17: Problem 51
Write the expression for the solubility-product constant for each of the following ionic compounds: AgI, SrSO \(_{4}, \mathrm{Fe}(\mathrm{OH})_{2},\) and \(\mathrm{Hg}_{2} \mathrm{Br}_{2}\) .
Chapter 17: Problem 51
Write the expression for the solubility-product constant for each of the following ionic compounds: AgI, SrSO \(_{4}, \mathrm{Fe}(\mathrm{OH})_{2},\) and \(\mathrm{Hg}_{2} \mathrm{Br}_{2}\) .
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Get started for freeYou have to prepare a \(\mathrm{pH}=5.00\) buffer, and you have the following 0.10 \(\mathrm{M}\) solutions available: HCOOH, HCOONa, \(\mathrm{CH}_{3} \mathrm{COOH}, \mathrm{CH}_{3} \mathrm{COONa}, \mathrm{HCN},\) and \(\mathrm{NaCN} .\) Which solutions would you use? How many milliliters of each solution would you use to make approximately 1 \(\mathrm{L}\) of the buffer?
Use values of \(K_{s p}\) for AgI and \(K_{f}\) for \(A g(C N)_{2}^{-}\) to (a) calculate the molar solubility of Agl in pure water, (b) calculate the equilibrium constant for the reaction \(\operatorname{AgI}(s)+2 \mathrm{CN}^{-}(a q) \rightleftharpoons \mathrm{Ag}(\mathrm{CN})_{2}^{-}(a q)+\mathrm{I}^{-}(a q), \quad(\mathbf{c})\) determine the molar solubility of AgI in a 0.100 \(\mathrm{MNaCN}\) solution.
For each of the following slightly soluble salts, write the net ionic equation, if any, for reaction with a strong acid: (a) MnS, \((\mathbf{b}) \mathrm{Pbl}_{2,}(\mathbf{c}) \mathrm{AuCl}_{3},(\mathbf{d}) \mathrm{Hg}_{2} \mathrm{C}_{2} \mathrm{O}_{4},\) (e) CuBr.
Predict whether the equivalence point of each of the following titrations is below, above, or at \(\mathrm{pH} 7 :(\mathbf{a}) \mathrm{NaHCO}_{3}\) titrated with \(\mathrm{NaOH},(\mathbf{b}) \mathrm{NH}_{3}\) titrated with \(\mathrm{HCl},(\mathbf{c}) \mathrm{KOH}\) titrated with HBr.
Mathematically prove that the \(\mathrm{pH}\) at the halfway point of a titration of a weak acid with a strong base (where the volume of added base is half of that needed to reach the equivalence point) is equal to p \(K_{a}\) for the acid.
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