Chapter 18: Problem 25
(a) What is the difference between chlorofluorocarbons and hydrofluorocarbons? (b) Why are hydrofluorocarbons potentially less harmful to the ozone layer than CFCs?
Chapter 18: Problem 25
(a) What is the difference between chlorofluorocarbons and hydrofluorocarbons? (b) Why are hydrofluorocarbons potentially less harmful to the ozone layer than CFCs?
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Get started for freeThe enthalpy of fusion of water is 6.01 \(\mathrm{kJ} / \mathrm{mol} .\) Sunlight striking Earth's surface supplies 168 \(\mathrm{W}\) per square meter \((1 \mathrm{W}=1\) watt \(=1 \mathrm{J} / \mathrm{s})\) . (a) Assuming that melting of ice is due only to energy input from the Sun, calculate how many grams of ice could be melted from a 1.00 square meter patch of ice over a 12 -h day. (b) The specific heat capacity of ice is 2.032 \(\mathrm{J} / \mathrm{g}^{\circ} \mathrm{C} .\) If the initial temperature of a 1.00 square meter patch of ice is \(-5.0^{\circ} \mathrm{C},\) what is its final temperature after being in sunlight for 12 \(\mathrm{h}\) , assuming no phase changes and assuming that sunlight penetrates uniformly to a depth of 1.00 \(\mathrm{cm} ?\)
(a) What is the primary basis for the division of the atmosphere into different regions? (b) Name the regions of the atmosphere, indicating the altitude interval for each one.
Bioremediation is the process by which bacteria repair their environment in response, for example, to an oil spill. The efficiency of bacteria for "eating" hydrocarbons depends on the amount of oxygen in the system, pH, temperature, and many other factors. In a certain oil spill, hydrocarbons from the oil disappeared with a first-order rate constant of \(2 \times 10^{-6} \mathrm{s}^{-1} .\) At that rate, how many days would it take for the hydrocarbons to decrease to 10\(\%\) of their initial value?
Write balanced chemical equations for each of the following reactions: (a) The nitric oxide molecule undergoes photodissociation in the upper atmosphere. (b) The nitric oxide molecule undergoes photoionization in the upper atmosphere. (c) Nitric oxide undergoes oxidation by ozone in the stratosphere. (d) Nitrogen dioxide dissolves in water to form nitric acid and nitric oxide.
The degradation of \(\mathrm{CF}_{3} \mathrm{CH}_{2} \mathrm{F}(\) an \(\mathrm{HFC})\) by \(\mathrm{OH}\) radicals in the troposphere is first order in each reactant and has a rate constant of \(k=1.6 \times 10^{8} M^{-1} \mathrm{s}^{-1}\) at \(4^{\circ} \mathrm{C} .\) If the tropospheric concentrations of \(\mathrm{OH}\) and \(\mathrm{CF}_{3} \mathrm{CH}_{2} \mathrm{F}\) are \(8.1 \times 10^{5}\)and \(6.3 \times 10^{8}\) molecules/cm\(^{3},\) respectively, what is the rate of reaction at this temperature in \(M / \mathrm{s} ?\)
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