Chapter 18: Problem 56
Discuss how catalysts can make processes more energy efficient.
Chapter 18: Problem 56
Discuss how catalysts can make processes more energy efficient.
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Get started for freeWhy is the photodissociation of \(\mathrm{N}_{2}\) in the atmosphere relatively unimportant compared with the photodissociation of \(\mathrm{O}_{2} ?\)
Bioremediation is the process by which bacteria repair their environment in response, for example, to an oil spill. The efficiency of bacteria for "eating" hydrocarbons depends on the amount of oxygen in the system, pH, temperature, and many other factors. In a certain oil spill, hydrocarbons from the oil disappeared with a first-order rate constant of \(2 \times 10^{-6} \mathrm{s}^{-1} .\) At that rate, how many days would it take for the hydrocarbons to decrease to 10\(\%\) of their initial value?
The Earth's oceans have a salinity of \(35 .\) What is the concentration of dissolved salts in seawater when expressed in ppm? What percentage of salts must be removed from sea-water before it can be considered freshwater (dissolved salts \(<500\) ppm \() ?[\operatorname{Section} 18.3]\)
One mystery in environmental science is the imbalance in the "carbon dioxide budget." Considering only human activities, scientists have estimated that 1.6 billion metric tons of \(\mathrm{CO}_{2}\) is added to the atmosphere every year because of deforestation (plants use \(\mathrm{CO}_{2},\) and fewer plants will leave more \(\mathrm{CO}_{2}\) in the atmosphere). Another 5.5 billion tons per year is put into the atmosphere because of burning fossil fuels. It is further estimated (again, considering only human activities) that the atmosphere actually takes up about 3.3 billion tons of this \(\mathrm{CO}_{2}\) per year, while the oceans take up 2 billion tons per year, leaving about 1.8 billion tons of \(\mathrm{CO}_{2}\) per year unaccounted for. Describe a mechanism by which \(\mathrm{CO}_{2}\) is removed from the atmosphere and ultimately ends up below the surface (Hint: What is the source of the fossil fuels?) [Sections \(18.1-18.3 ]\)
A first-stage recovery of magnesium from seawater is precipitation of \(\mathrm{Mg}(\mathrm{OH})_{2}\) with CaO: $$\mathrm{Mg}^{2+}(a q)+\mathrm{CaO}(s)+\mathrm{H}_{2} \mathrm{O}(l) \longrightarrow \mathrm{Mg}(\mathrm{OH})_{2}(s)+\mathrm{Ca}^{2+}(a q)$$ What mass of \(\mathrm{CaO},\) in grams, is needed to precipitate 1000 lb of \(\mathrm{Mg}(\mathrm{OH})_{2} ?\)
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