Chapter 18: Problem 65
What properties of CFCs make them ideal for various commercial applications but also make them a long-term problem in the stratosphere?
Chapter 18: Problem 65
What properties of CFCs make them ideal for various commercial applications but also make them a long-term problem in the stratosphere?
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Get started for freeThe Henry's law constant for \(\mathrm{CO}_{2}\) in water at \(25^{\circ} \mathrm{C}\) is \(3.1 \times 10^{-2} \mathrm{Matm}^{-1}\) . (a) What is the solubility of \(\mathrm{CO}_{2}\) in water at this temperature if the solution is in contact with air at normal atmospheric pressure? (b) Assume that all of this \(\mathrm{CO}_{2}\) is in the form of \(\mathrm{H}_{2} \mathrm{CO}_{3}\) produced by the reaction between \(\mathrm{CO}_{2}\) and \(\mathrm{H}_{2} \mathrm{O} :\) $$\mathrm{CO}_{2}(a q)+\mathrm{H}_{2} \mathrm{O}(l) \longrightarrow \mathrm{H}_{2} \mathrm{CO}_{3}(a q)$$ What is the pH of this solution?
Which of the following reactions in the stratosphere cause an increase in temperature there? \begin{equation}\begin{array}{l}{\text { (a) } \mathrm{O}(g)+\mathrm{O}_{2}(g) \longrightarrow \mathrm{O}_{3}^{*}(g)} \\ {\text { (b) } \mathrm{O}_{3}^{\star}(g)+\mathrm{M}(g) \longrightarrow \mathrm{O}_{3}(g)+\mathrm{M}^{\star}(g)} \\ {\text { (c) } \mathrm{O}_{2}(g)+h \nu \longrightarrow 2 \mathrm{O}(g)}\\\\{\text { (d) } \mathrm{O}(g)+\mathrm{N}_{2}(g) \longrightarrow \mathrm{NO}(g)+\mathrm{N}(g)} \\\ {\text { (e) All of the above }}\end{array}\end{equation}
In 1986 an electrical power plant in Taylorsville, Georgia, burned \(8,376,726\) tons of coal, a national record at that time. (a) Assuming that the coal was 83\(\%\) carbon and 2.5\(\%\) sulfur and that combustion was complete, calculate the number of tons of carbon dioxide and sulfur dioxide produced by the plant during the year. (b) If 55\(\%\) of the SO \(_{2}\) could be removed by reaction with powdered CaO to form \(\mathrm{CaSO}_{3},\) how many tons of \(\mathrm{CaSO}_{3}\) would be produced?
Bioremediation is the process by which bacteria repair their environment in response, for example, to an oil spill. The efficiency of bacteria for "eating" hydrocarbons depends on the amount of oxygen in the system, pH, temperature, and many other factors. In a certain oil spill, hydrocarbons from the oil disappeared with a first-order rate constant of \(2 \times 10^{-6} \mathrm{s}^{-1} .\) At that rate, how many days would it take for the hydrocarbons to decrease to 10\(\%\) of their initial value?
In \(\mathrm{CF}_{3} \mathrm{Cl}\) the \(\mathrm{C}-\mathrm{Cl}\) bond- dissociation energy is 339 \(\mathrm{kJ} / \mathrm{mol} .\) In \(\mathrm{CCl}_{4}\) the \(\mathrm{C}-\mathrm{Cl}\) bond dissociation energy is 293 \(\mathrm{kJ} / \mathrm{mol} .\) What is the range of wavelengths of photons that can cause \(\mathrm{C}-\mathrm{Cl}\) bond rupture in one molecule but not in the other?
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