Chapter 20: Problem 61
(a) In the Nernst equation, what is the numerical value of the reaction quotient, Q, under standard conditions? (b) Can the Nernst equation be used at temperatures other than room temperature?
Chapter 20: Problem 61
(a) In the Nernst equation, what is the numerical value of the reaction quotient, Q, under standard conditions? (b) Can the Nernst equation be used at temperatures other than room temperature?
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Get started for freeCopper corrodes to cuprous oxide, \(\mathrm{Cu}_{2} \mathrm{O},\) or cupric oxide, \(\mathrm{CuO},\) depending on environmental conditions. (a) What is the oxidation state of copper in cuprous oxide? (b) What is the oxidation state of copper in cupric oxide? (c) Copper peroxide is another oxidation product of elemental copper. Suggest a formula for copper peroxide based on its name. (d) Copper(III) oxide is another unusual oxidation product of elemental copper. Suggest a chemical formula for copper(II) oxide.
Is each of the following substances likely to serve as an oxidant or a reductant: (a) \(\mathrm{Ce}^{3+}(a q),\)(b) \(\mathrm{Ca}(s),\) (c) \(\mathrm{ClO}_{3}(a q)\) (d) \(\mathrm{N}_{2} \mathrm{O}_{5}(g) ?\)
Mercuric oxide dry-cell batteries are often used where a flat discharge voltage and long life are required, such as in watches and cameras. The two half-cell reactions that occur in the battery are $$ \begin{array}{l}{\mathrm{HgO}(s)+\mathrm{H}_{2} \mathrm{O}(l)+2 \mathrm{e}^{-} \longrightarrow \mathrm{Hg}(l)+2 \mathrm{OH}^{-}(a q)} \\ {\mathrm{Zn}(s)+2 \mathrm{OH}^{-}(a q) \longrightarrow \mathrm{znO}(s)+\mathrm{H}_{2} \mathrm{O}(l)+2 \mathrm{e}^{-}}\end{array} $$ (a) Write the overall cell reaction. (b) The value of \(E_{\text { red }}^{\circ}\) for the cathode reaction is \(+0.098 \mathrm{V}\) . The overall cell potential is \(+1.35 \mathrm{V}\) . Assuming that both half-cells operate under standard conditions, what is the standard reduction potential for the anode reaction? (c) Why is the potential of the anode reaction different than would be expected if the reaction occurred in an acidic medium?
A 1 M solution of \(\mathrm{Cu}\left(\mathrm{NO}_{3}\right)_{2}\) is placed in a beaker with a strip of Cu metal. A 1 \(\mathrm{M}\) solution of \(\mathrm{SnSO}_{4}\) is placed in a second beaker with a strip of Sn metal. A salt bridge connects the two beakers, and wires to a voltmeter link two metal electrodes. (a) Which electrode serves as the anode, and which as the cathode? (b) Which electrode gains mass, and which loses mass as the cell reaction proceeds? (c) Write the equation for the overall cell reaction. (d) What is the emf generated by the cell under standard conditions?
At 298 \(\mathrm{K}\) a cell reaction has a standard cell potential of \(+0.17 \mathrm{V} .\) The equilibrium constant for the reaction is \(5.5 \times 10^{5} .\) What is the value of \(n\) for the reaction?
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