Chapter 22: Problem 27
Describe two characteristics of hydrogen that are favorable for its use as a general energy source in vehicles.
Chapter 22: Problem 27
Describe two characteristics of hydrogen that are favorable for its use as a general energy source in vehicles.
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Get started for freeWrite a balanced equation for each of the following reactions: (a) preparation of white phosphorus from calcium phosphate, (b) hydrolysis of PBry, (c) reduction of PBr_ to \(P_{4}\) in the gas phase, using \(\mathrm{H}_{2}\) .
Ultrapure germanium, like silicon, is used in semiconductors. Germanium of "ordinary" purity is prepared by the high-temperature reduction of \(\mathrm{GeO}_{2}\) with carbon. The Ge is converted to GeCl_ by treatment with \(\mathrm{Cl}_{2}\) and then purified by distillation; GeCl_ is then hydrolyzed in water to GeO \(_{2}\) and reduced to the elemental form with \(\mathrm{H}_{2}\) . The element is then zone refined. Write a balanced chemical equation for each of the chemical transformations in the course of forming ultrapure Ge from GeO \(_{2} .\)
Complete and balance the following equations: $$\begin{array}{l}{\text { (a) } \mathrm{NaOCH}_{3}(s)+\mathrm{H}_{2} \mathrm{O}(l) \longrightarrow} \\ {\text { (b) } \mathrm{CuO}(s)+\mathrm{HNO}_{3}(a q) \longrightarrow} \\ {\text { (c) } \mathrm{WO}_{3}(s)+\mathrm{H}_{2}(g) \stackrel{\Delta}{\longrightarrow}}\end{array}$$ $$\begin{array}{l}{\text { (d) } \mathrm{NH}_{2} \mathrm{OH}(l)+\mathrm{O}_{2}(g) \longrightarrow} \\ {\text { (e) } \mathrm{Al}_{4} \mathrm{C}_{3}(s)+\mathrm{H}_{2} \mathrm{O}(l) \longrightarrow}\end{array}$$
Explain each of the following observations: (a) At room temperature I \(_{2}\) is a solid, Br \(_{2}\) is a liquid, and \(C l_{2}\) and \(F_{2}\) are both gases. (b) \(F_{2}\) cannot be prepared by electrolytic oxidation of aqueous \(\mathrm{F}^{-}\) solutions. (c) The boiling point of HF is much higher than those of the other hydrogen halides. (d) The halogens decrease in oxidizing power in the order \(\mathrm{F}_{2}>\mathrm{Cl}_{2}>\mathrm{Br}_{2}>\mathrm{I}_{2} .\)
Consider the elements Li, \(\mathrm{K}, \mathrm{Cl}, \mathrm{C}, \mathrm{Ne},\) and Ar. From this list, select the element that (a) is most electronegative, (b) has the greatest metallic character, (c) most readily forms a positive ion, (d) has the smallest atomic radius, (e) forms \(\pi\) bonds most readily, (f) has multiple allotropes.
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