Complete and balance the following equations: $$\begin{array}{l}{\text { (a) } \mathrm{CaO}(s)+\mathrm{H}_{2} \mathrm{O}(l) \longrightarrow} \\ {\text { (b) } \mathrm{Al}_{2} \mathrm{O}_{3}(s)+\mathrm{H}^{+}(a q) \longrightarrow} \\\ {\text { (c) } \mathrm{Na}_{2} \mathrm{O}_{2}(s)+\mathrm{H}_{2} \mathrm{O}(l) \longrightarrow}\end{array}$$ $$ \begin{array}{l}{\text {(d) } \mathrm{N}_{2} \mathrm{O}_{3}(g)+\mathrm{H}_{2} \mathrm{O}(l) \longrightarrow} \\ {\text { (e) } \mathrm{KO}_{2}(s)+\mathrm{H}_{2} \mathrm{O}(l) \longrightarrow} \\ {\text { (f) } \mathrm{NO}(g)+\mathrm{O}_{3}(g) \longrightarrow}\end{array} $$

Short Answer

Expert verified
The balanced equations are: (a) \(\mathrm{CaO}(s)+\mathrm{H}_{2} \mathrm{O}(l) \longrightarrow \mathrm{Ca(OH)}_{2}(s)\) (b) \(\mathrm{Al}_{2} \mathrm{O}_{3}(s)+6\mathrm{H}^{+}(a q) \longrightarrow 2\mathrm{Al}^{3+}(a q)+3\mathrm{H}_{2} \mathrm{O}(l)\) (c) \(\mathrm{Na}_{2} \mathrm{O}_{2}(s)+2\mathrm{H}_{2} \mathrm{O}(l) \longrightarrow 2\mathrm{NaOH}(a q)+\mathrm{O}_{2}(g)\) (d) \(\mathrm{N}_{2} \mathrm{O}_{3}(g)+\mathrm{H}_{2} \mathrm{O}(l) \longrightarrow 2\mathrm{HNO}_{3}(a q)\) (e) \(2\mathrm{KO}_{2}(s)+2\mathrm{H}_{2} \mathrm{O}(l) \longrightarrow 2\mathrm{KOH}(a q)+\mathrm{O}_{2}(g)+2\mathrm{H}_{2} \mathrm{O}_{2}(l)\) (f) \(\mathrm{NO}(g)+\mathrm{O}_{3}(g) \longrightarrow \mathrm{NO}_{2}(g)+\mathrm{O}_{2}(g)\)

Step by step solution

01

Equation (a) Completion

The given equation is: $$\mathrm{CaO}(s)+\mathrm{H}_{2} \mathrm{O}(l) \longrightarrow?$$ Calcium oxide (CaO) reacts with water (H₂O) to produce calcium hydroxide (Ca(OH)₂): $$\mathrm{CaO}(s)+\mathrm{H}_{2} \mathrm{O}(l) \longrightarrow \mathrm{Ca(OH)}_{2}(s)$$
02

Equation (a) Balancing

The equation is already balanced.
03

Equation (b) Completion

The given equation is: $$\mathrm{Al}_{2} \mathrm{O}_{3}(s)+\mathrm{H}^{+}(a q) \longrightarrow?$$ Aluminum oxide (Al₂O₃) reacts with hydrogen ions (H⁺) to produce aluminum ions (Al³⁺) and water (H₂O): $$\mathrm{Al}_{2} \mathrm{O}_{3}(s)+\mathrm{H}^{+}(a q) \longrightarrow \mathrm{Al}^{3+}(a q)+\mathrm{H}_{2} \mathrm{O}(l)$$
04

Equation (b) Balancing

Balancing the equation, we get: $$\mathrm{Al}_{2} \mathrm{O}_{3}(s)+6\mathrm{H}^{+}(a q) \longrightarrow 2\mathrm{Al}^{3+}(a q)+3\mathrm{H}_{2} \mathrm{O}(l)$$
05

Equation (c) Completion

Given equation: $$\mathrm{Na}_{2} \mathrm{O}_{2}(s)+\mathrm{H}_{2} \mathrm{O}(l) \longrightarrow?$$ Sodium peroxide (Na₂O₂) reacts with water (H₂O) to produce sodium hydroxide (NaOH) and oxygen (O₂) gas: $$\mathrm{Na}_{2} \mathrm{O}_{2}(s)+\mathrm{H}_{2} \mathrm{O}(l) \longrightarrow \mathrm{NaOH}(a q)+\mathrm{O}_{2}(g)$$
06

Equation (c) Balancing

Balanced equation: $$\mathrm{Na}_{2} \mathrm{O}_{2}(s)+2\mathrm{H}_{2} \mathrm{O}(l) \longrightarrow 2\mathrm{NaOH}(a q)+\mathrm{O}_{2}(g)$$
07

Equation (d) Completion

Given equation: $$\mathrm{N}_{2} \mathrm{O}_{3}(g)+\mathrm{H}_{2} \mathrm{O}(l) \longrightarrow?$$ Dinitrogen trioxide (N₂O₃) reacts with water (H₂O) to produce nitric acid (HNO₃): $$\mathrm{N}_{2} \mathrm{O}_{3}(g)+\mathrm{H}_{2} \mathrm{O}(l) \longrightarrow \mathrm{HNO}_{3}(a q)$$
08

Equation (d) Balancing

Balanced equation: $$\mathrm{N}_{2} \mathrm{O}_{3}(g)+\mathrm{H}_{2} \mathrm{O}(l) \longrightarrow 2\mathrm{HNO}_{3}(a q)$$
09

Equation (e) Completion

Given equation: $$\mathrm{KO}_{2}(s)+\mathrm{H}_{2} \mathrm{O}(l) \longrightarrow?$$ Potassium superoxide (KO₂) reacts with water (H₂O) to produce potassium hydroxide (KOH), oxygen (O₂) gas, and hydrogen peroxide (H₂O₂): $$\mathrm{KO}_{2}(s)+\mathrm{H}_{2} \mathrm{O}(l) \longrightarrow \mathrm{KOH}(a q)+\mathrm{O}_{2}(g)+\mathrm{H}_{2} \mathrm{O}_{2}(l)$$
10

Equation (e) Balancing

Balanced equation: $$2\mathrm{KO}_{2}(s)+2\mathrm{H}_{2} \mathrm{O}(l) \longrightarrow 2\mathrm{KOH}(a q)+\mathrm{O}_{2}(g)+2\mathrm{H}_{2} \mathrm{O}_{2}(l)$$
11

Equation (f) Completion

Given equation: $$\mathrm{NO}(g)+\mathrm{O}_{3}(g) \longrightarrow?$$ Nitric oxide (NO) reacts with ozone (O₃) to produce nitrogen dioxide (NO₂) and oxygen (O₂) gas: $$\mathrm{NO}(g)+\mathrm{O}_{3}(g) \longrightarrow \mathrm{NO}_{2}(g)+\mathrm{O}_{2}(g)$$
12

Equation (f) Balancing

The equation is already balanced.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Chemical Reaction Completion
Understanding the completion of chemical reactions is a crucial part of inorganic chemistry and involves predicting the products of a given set of reactants. A reaction is said to be complete when all reactants have been converted to products under the reaction conditions. When you encounter a problem like this in your homework, it's important to recall common reaction types such as synthesis, decomposition, single replacement, and double replacement reactions.

For instance, when calcium oxide reacts with water, through a synthesis reaction, it forms calcium hydroxide. Also, certain reactions may result in more complex product formation, such as the reaction of potassium superoxide with water producing both potassium hydroxide, oxygen gas, and hydrogen peroxide, showcasing a multi-step process. Understanding the nature of the reactants is key to predicting the correct products and thereby completing the chemical reaction. Always remember to check your predicted products against known chemical behavior and reaction patterns.
Stoichiometry
Stoichiometry is at the heart of chemical equations and is the quantitative relationship between reactants and products in a chemical reaction. It is based on the conservation of mass and the concept of the mole. Once the chemical reaction is completed, the next step is balancing the equation to ensure that the number of atoms for each element is the same on both sides of the equation.

When balancing chemical equations, such as those for aluminum oxide reacting with hydrogen ions or sodium peroxide with water, it’s essential to identify the mole ratio of the reactants and products, which follows from the stoichiometric coefficients in the balanced equation. For example, in the reaction involving aluminum oxide reacting with hydrogen ions, the balanced equation indicates that one mole of aluminum oxide reacts with six moles of hydrogen ions, yielding two moles of aluminum ions and three moles of water. The stoichiometry of a reaction helps to predict how much product will be formed from given amounts of reactants, which is essential not only for answering homework problems but also for practical applications in everyday chemical reactions and industrial processes.
Inorganic Chemistry
Inorganic chemistry is the branch of chemistry that deals with the properties and behavior of inorganic compounds, which typically include metals, minerals, and organometallic compounds. The reactions provided in the exercise are classic examples of inorganic reactions where simple compounds—often consisting of ionic bonds—undergo chemical changes. For instance, the oxide forms of elements such as in the reactions of calcium oxide (CaO), aluminum oxide (Al2O3), sodium peroxide (Na2O2), and potassium superoxide (KO2) with water show different products according to their chemical nature.

Inorganic reactions can involve a variety of reaction types, such as acid-base reactions, redox reactions, and precipitation reactions. Understanding the principles of inorganic chemistry, such as periodic table trends, oxidation states, and the nature of chemical bonds, is essential to solving the balance and completion of chemical equations. This branch of chemistry is essential not only for academic purposes but also has vast applications in fields like medicine, materials science, and environmental sciences, to name a few.

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Most popular questions from this chapter

Consider the elements Li, \(\mathrm{K}, \mathrm{Cl}, \mathrm{C}, \mathrm{Ne},\) and Ar. From this list, select the element that (a) is most electronegative, (b) has the greatest metallic character, (c) most readily forms a positive ion, (d) has the smallest atomic radius, (e) forms \(\pi\) bonds most readily, (f) has multiple allotropes.

Which of the following statements are true? (a) Si can form an ion with six fluorine atoms, SiF \(_{6}^{2-}\) ,whereas carbon cannot.(b) Si can form three stable compounds containing two Si atoms each, \(\mathrm{Si}_{2} \mathrm{H}_{2}, \mathrm{Si}_{2} \mathrm{H}_{4},\) and \(\mathrm{Si}_{2} \mathrm{H}_{6}\) (c) In \(\mathrm{HNO}_{3}\) and \(\mathrm{H}_{3} \mathrm{PO}_{4}\) the central atoms, \(\mathrm{N}\) and \(\mathrm{P},\) have different oxidation states. (d) \(\mathrm{S}\) is more electronegative than Se.

Write the chemical formula for each of the following, and indicate the oxidation state of the halogen or noble-gas atom in each: (a) calcium hypobromite, (b) bromic acid, (c) xenon trioxide, (d) perchlorate ion, (e) iodous acid,(f) iodine pentafluoride.

Hydrogen peroxide is capable of oxidizing (a) hydrazine to \(\mathrm{N}_{2}\) and \(\mathrm{H}_{2} \mathrm{O},(\mathbf{b}) \mathrm{SO}_{2}\) to \(\mathrm{SO}_{4}^{2-},(\mathbf{c}) \mathrm{NO}_{2}^{-}\) to \(\mathrm{NO}_{3}^{-},(\mathbf{d}) \mathrm{H}_{2} \mathrm{S}(g)\) \(\mathrm{to} S(s),(\mathbf{e}) \mathrm{Fe}^{2+}\) to \(\mathrm{Fe}^{3+} .\) Write a balanced net ionic equation for each of these redox reactions.

Borazine, \((\mathrm{BH})_{3}(\mathrm{NH})_{3},\) is an analog of \(\mathrm{C}_{6} \mathrm{H}_{6},\) benzene. It can be prepared from the reaction of diborane with ammonia, with hydrogen as another product; or from lithium borohydride and ammonium chloride, with lithium chloride and hydrogen as the other products. (a) Write balanced chemical equations for the production of borazine using both synthetic methods. (b) Draw the Lewis dot structure of borazine. (c) How many grams of borazine can be prepared from 2.00 L of ammonia at STP, assuming diborane is in excess?

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