Chapter 23: Problem 17
Which type of substance is attracted by a magnetic field, a diamagnetic substance or a paramagnetic substance?
Chapter 23: Problem 17
Which type of substance is attracted by a magnetic field, a diamagnetic substance or a paramagnetic substance?
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Get started for freeIndicate the coordination number and the oxidation number of the metal for each of the following complexes: (a) \(\mathrm{Na}_{2}\left[\mathrm{CdCl}_{4}\right]\) (b) \(\mathrm{K}_{2}\left[\mathrm{MoOCl}_{4}\right]\) (c) \(\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{4} \mathrm{Cl}_{2}\right] \mathrm{Cl}\) (d) \(\left[\mathrm{Ni}(\mathrm{CN})_{5}\right]^{3-}\) (e) \(\mathrm{K}_{3}\left[\mathrm{V}\left(\mathrm{C}_{2} \mathrm{O}_{4}\right)_{3}\right]\) (f) \(\left[\mathrm{Zn}(\mathrm{en})_{2}\right] \mathrm{Br}_{2}\)
Consider an octahedral complex \(\mathrm{MA}_{3} \mathrm{B}_{3} .\) How many geo- metric isomers are expected for this compound? Will any of the isomers be optically active? If so, which ones?
Determine if each of the following complexes exhibits geometric isomerism. If geometric isomers exist, determine how many there are. (a) tetrahedral \(\left[\operatorname{Cd}\left(\mathrm{H}_{2} \mathrm{O}\right)_{2} \mathrm{Cl}_{2}\right],(\mathbf{b})\) square-planar \(\left[\operatorname{IrCl}_{2}\left(\mathrm{PH}_{3}\right)_{2}\right]^{-},(\mathbf{c})\) octahedral \(\left[\mathrm{Fe}(o-\mathrm{phen})_{2} \mathrm{Cl}_{2}\right]^{+}.\)
For each of the following metals, write the electronic configuration of the atom and its \(3+\) ion: (a) Fe, (b) Mo, (c) Co. Draw the crystal-field energy- level diagram for the \(d\) orbitals of an octahedral complex, and show the placement of the \(d\) electrons for each \(3+\) ion, assuming a weak-field complex. How many unpaired electrons are there in each case?
Which transition metal atom is present in each of the following biologically important molecules: (a) hemoglobin, (b) chlorophyls, (c) siderophores, (d) hemocyanine.
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