Draw all structural and geometric isomers of butene and name them.

Short Answer

Expert verified
The four isomers of butene are: 1-butene, cis-2-butene, trans-2-butene, and 2-methylpropene.

Step by step solution

01

Identify the different possible arrangements of carbon atoms

For butene, there are two ways in which four carbon atoms can be arranged: 1. A four-carbon continuous chain (butene) 2. A three-carbon chain with one branch (methylpropene) We will examine both of these arrangements and consider different isomers.
02

Draw all possible isomers for a four-carbon continuous chain (butene) and identify geometric isomers

For a four-carbon continuous chain, there are two possible positions for the carbon-carbon double bond: between the first and second carbons, or between the second and third carbons. Thus, there are two possible structures for butene: 1. 1-butene: In this isomer, the carbon-carbon double bond is between the first and second carbons. As there are no different groups attached to the double bond, there are no geometric isomers for this structure. 2. 2-butene: In this isomer, the carbon-carbon double bond is between the second and third carbons. Here, there are different groups attached to the double bond, leading to two possible geometric isomers: cis-2-butene and trans-2-butene. - Cis-2-butene: In this geometric isomer, the two methyl groups (CH3) are on the same side of the carbon-carbon double bond. - Trans-2-butene: In this geometric isomer, the two methyl groups are on the opposite sides of the carbon-carbon double bond.
03

Draw the possible isomers for a three-carbon continuous chain (methylpropene)

For a three-carbon continuous chain with one branch, there is only one possible position for the methyl group (CH3) to be attached, as well as only one possible position for the carbon-carbon double bond. This leads to only one possible structure for methylpropene: 1. 2-methylpropene: In this isomer, the carbon-carbon double bond is between the first and second carbons, and the methyl group is attached to the second carbon atom. Just like 1-butene, there are no geometric isomers for this structure due to the lack of different groups attached to the double bond, In conclusion, there are four isomers for butene: 1-butene, cis-2-butene, trans-2-butene, and 2-methylpropene.

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