Chapter 24: Problem 54
Acetic anhydride is formed from two acetic acid molecules, in a condensation reaction that involves the removal of a molecule of water. Write the chemical equation for this process, and show the structure of acetic anhydride.
Chapter 24: Problem 54
Acetic anhydride is formed from two acetic acid molecules, in a condensation reaction that involves the removal of a molecule of water. Write the chemical equation for this process, and show the structure of acetic anhydride.
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Get started for freeThe molar heat of combustion of gaseous cyclopropane is \(-2089 \mathrm{kJ} / \mathrm{mol};\) that for gaseous cyclopentane is \(-3317 \mathrm{kJ} / \mathrm{mol} .\) Calculate the heat of combustion per \(\mathrm{CH}_{2}\) group in the two cases, and account for the difference.
Write a condensed structural formula for each of the following: (a) an acid with the formula \(\mathrm{C}_{4} \mathrm{H}_{8} \mathrm{O}_{2},\) (b) a cyclic ketone with the formula \(\mathrm{C}_{5} \mathrm{H}_{8} \mathrm{O},(\mathbf{c})\) a dihydroxy compound with the formula \(\mathrm{C}_{3} \mathrm{H}_{8} \mathrm{O}_{2},(\mathbf{d})\) a cyclic ester with the formula \(\mathrm{C}_{5} \mathrm{H}_{8} \mathrm{O}_{2} .\)
(a) Are \(\alpha\) -glucose and \(\beta\) -glucose enantiomers? (b) Show the condensation of two glucose molecules to form a disaccharide with an \(\alpha\) linkage. (c) Repeat part (b) but with a \(\beta\) linkage.
Write the condensed structural formulas for two alkenes and one alkyne that all have the molecular formula \(\mathrm{C}_{6} \mathrm{H}_{10}\) .
You have samples of four compounds: dimethyl ether, methane, difluoromethane, and ethanol. You measure the boiling points of the compounds as \(-128^{\circ} \mathrm{C},-52^{\circ} \mathrm{C}\) \(-25^{\circ} \mathrm{C},\) and \(78^{\circ} \mathrm{C},\) but then lose the labels for each sample. Make the following predictions: (a) Which compound boils at \(-128^{\circ} \mathrm{C} ?(\mathbf{b})\) Which boils at \(-52^{\circ} \mathrm{C} ?(\mathbf{c})\) Which boils at \(-25^{\circ} \mathrm{C} ?(\mathbf{d})\) Which boils at \(78^{\circ} \mathrm{C} ?\)
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