Chapter 3: Problem 49
A compound whose empirical formula is \(X F_{3}\) consists of 65\(\%\) F by mass. What is the atomic mass of \(X ?\)
Chapter 3: Problem 49
A compound whose empirical formula is \(X F_{3}\) consists of 65\(\%\) F by mass. What is the atomic mass of \(X ?\)
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Get started for freeOne of the most bizarre reactions in chemistry is called the Ugi reaction: $$ \begin{array}{l}{\mathrm{R}_{1} \mathrm{C}(=\mathrm{O}) \mathrm{R}_{2}+\mathrm{R}_{3}-\mathrm{NH}_{2}+\mathrm{R}_{4} \mathrm{COOH}+\mathrm{R}_{5} \mathrm{NC} \rightarrow} \\ {\mathrm{R}_{4} \mathrm{C}(=\mathrm{O}) \mathrm{N}\left(\mathrm{R}_{3}\right) \mathrm{C}\left(\mathrm{R}_{1} \mathrm{R}_{2}\right) \mathrm{C}=\mathrm{ONHR}_{5}+\mathrm{H}_{2} \mathrm{O}}\end{array} $$ (a) Write out the balanced chemical equation for the Ugi reaction, for the case where \(R=C H_{3} C H_{2} C H_{2} C H_{2} C H_{2} C H_{2}-\) (this is called the hexyl group) for all compounds. (b) What mass of the "hexyl Ugi product" would you form if 435.0 \(\mathrm{mg}\) of \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{NH}_{2}\) was the limiting reactant?
(a) What is the mass, in grams, of 1.223 mol of iron( III) sulfate? (b) How many moles of ammonium ions are in 6.955 g of ammonium carbonate? (c) What is the mass, in grams, of \(1.50 \times 10^{21}\) molecules of aspirin, \(\mathrm{C}_{9} \mathrm{H}_{8} \mathrm{O}_{4} ?\) (d) What is the molar mass of diazepam (Valium') if 0.05570 mol has a mass of 15.86 \(\mathrm{g} ?\)
The fizz produced when an Alka-Seltzer tablet is dissolved in water is due to the reaction between sodium bicarbonate \(\left(\mathrm{NaHCO}_{3}\right)\) and citric acid \(\left(\mathrm{H}_{3} \mathrm{C}_{6} \mathrm{H}_{5} \mathrm{O}_{7}\right) :\) $$ \begin{aligned} 3 \mathrm{NaHCO}_{3}(a q)+\mathrm{H}_{3} \mathrm{C}_{6} \mathrm{H}_{5} \mathrm{O}_{7}(a q) & \longrightarrow \\ & 3 \mathrm{CO}_{2}(g)+3 \mathrm{H}_{2} \mathrm{O}(l)+\mathrm{Na}_{3} \mathrm{C}_{6} \mathrm{H}_{5} \mathrm{O}_{7}(a q) \end{aligned} $$ In a certain experiment 1.00 g of sodium bicarbonate and 1.00 g of citric acid are allowed to react. (a) Which is the limiting reactant? (b) How many grams of carbon dioxide form? (c) How many grams of the excess reactant remain after the limiting reactant is completely consumed?
What is the mass, in kilograms, of an Avogadro's number of people, if the average mass of a person is 160 \(\mathrm{lb}\) ? How does this compare with the mass of Earth, \(5.98 \times 10^{24} \mathrm{kg}\) ?
A piece of aluminum foil 1.00 \(\mathrm{cm}^{2}\) and 0.550 -mm thick is allowed to react with bromine to form aluminum bromide. (a) How many moles of aluminum were used? (The density of aluminum is 2.699 \(\mathrm{g} / \mathrm{cm}^{3} .\) ) (b) How many grams of aluminum bromide form, assuming the aluminum reacts completely?
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