A piece of aluminum foil 1.00 \(\mathrm{cm}^{2}\) and 0.550 -mm thick is allowed to react with bromine to form aluminum bromide. (a) How many moles of aluminum were used? (The density of aluminum is 2.699 \(\mathrm{g} / \mathrm{cm}^{3} .\) ) (b) How many grams of aluminum bromide form, assuming the aluminum reacts completely?

Short Answer

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(a) About 0.00548 moles of aluminum were used. (b) About 1.46 grams of aluminum bromide were formed, assuming the aluminum reacts completely.

Step by step solution

01

Calculate the volume of aluminum

To find the mass of the aluminum piece, we first need to find its volume. Since the area is 1.00 cm² and the thickness is 0.550 mm, we can convert the thickness to cm and calculate the volume. Thickness in cm = 0.550 mm × (1 cm / 10 mm) = 0.0550 cm Volume = area × thickness = 1.00 cm² × 0.0550 cm = 0.0550 cm³
02

Calculate the mass of aluminum

Now, we can use the density of aluminum (2.699 g/cm³) to find the mass of the aluminum piece. Density = mass / volume mass = density × volume = 2.699 g/cm³ × 0.0550 cm³ = 0.148 g Step 2: Convert the mass of aluminum to moles
03

Calculate the moles of aluminum

We will now need to use the molar mass of aluminum to find the number of moles in the 0.148 g piece. Molar mass of aluminum = 26.98 g/mol Moles of aluminum = mass / molar mass = 0.148 g / 26.98 g/mol ≈ 0.00548 mol Step 3: Find the mass of aluminum bromide formed
04

Calculate the moles of aluminum bromide

Aluminum reacts with bromine to form aluminum bromide according to the following balanced chemical equation: 2 Al (s) + 3 Br₂ (l) -> 2 AlBr₃ (s) From the balanced equation, we can see that for every 1 mole of aluminum, 1 mole of aluminum bromide is formed. Hence, moles of aluminum bromide formed = 0.00548 mol.
05

Calculate the mass of aluminum bromide

Now, using the molar mass of aluminum bromide, we can calculate the mass of aluminum bromide formed. Molar mass of AlBr₃ = (1 × 26.98 g/mol) + (3 × 79.90 g/mol) = 266.68 g/mol Mass of AlBr₃ = moles × molar mass = 0.00548 mol × 266.68 g/mol ≈ 1.46 g Answer: (a) About 0.00548 moles of aluminum were used. (b) About 1.46 grams of aluminum bromide were formed, assuming the aluminum reacts completely.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Mole Concept
Understanding the mole concept is fundamental in solving stoichiometry problems. A mole is a unit in chemistry that signifies a specific number of particles, atoms, ions, or molecules. This specific number, known as Avogadro's number, is approximately \(6.022 \times 10^{23}\) entities and is consistent for all substances.

For instance, in calculating the moles of aluminum used in the given problem, we first found the mass of the aluminum foil and then applied the mole concept. By dividing the mass of aluminum by its molar mass (the mass of one mole of aluminum), we were able to determine the number of moles present. This concept connects the microscopic particles to macroscopic measurements we can easily handle in the laboratory.

When applying the mole concept to chemical equations, it's crucial to consider the stoichiometry of the reaction, which tells us the proportional relationship between reactants and products in a balanced equation. It is through this concept that we can convert moles of one substance to moles of another, using the mole ratios derived from the balanced equation.
Chemical Reactions
Chemical reactions involve the transformation of reactants into products through the breaking and forming of chemical bonds. Writing a balanced chemical equation is an essential step in solving stoichiometry problems. A balanced equation obeys the Law of Conservation of Mass, ensuring that the number of atoms for each element is the same on both sides of the equation.

In our problem, the balanced chemical equation for the reaction between aluminum and bromine to form aluminum bromide is:\[2 \text{Al (s)} + 3 \text{Br}_2 (l) \rightarrow 2 \text{AlBr}_3 (s)\]
This tells us that two moles of aluminum will react with three moles of bromine to produce two moles of aluminum bromide. Understanding the stoichiometry of this reaction is crucial as it allows us to predict the amounts of reactants and products involved. Once we know the moles of aluminum, the equation guides us to find the moles of aluminum bromide formed, given the mole-to-mole conversion between reactants and products.
Molar Mass
The molar mass is the mass of one mole of a given substance, usually expressed in grams per mole (g/mol). It is a bridge between the atomic or molecular scale and the macroscopic scale, which we use to weigh substances. To find the molar mass of a compound, such as aluminum bromide (AlBr₃), you sum up the molar masses of the individual atoms within the molecule. Each element's molar mass is found on the periodic table and represents the mass of one mole of atoms of that element.

For example, to calculate the molar mass of AlBr₃, we added three times the molar mass of bromine to the molar mass of aluminum. Knowing the molar mass allowed us to convert between moles and grams, a key step in solving the problem. In stoichiometry problems, after determining the number of moles of a substance involved in a reaction, the molar mass is used to translate this amount into a measurable quantity, such as grams, which is more practical for laboratory work.

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Most popular questions from this chapter

Determine the empirical and molecular formulas of each of the following substances: (a) Styrene, a compound used to make Styrofoam' cups and insulation, contains 92.3\(\% \mathrm{C}\) and 7.7\(\% \mathrm{H}\) by mass and has a molar mass of 104 \(\mathrm{g} / \mathrm{mol} .\) (b) Caffeine, a stimulant found in coffee, contains 49.5\(\% \mathrm{C}\) , \(5.15 \% \mathrm{H}, 28.9 \% \mathrm{N},\) and 16.5\(\% \mathrm{O}\) by mass and has a molar mass of 195 \(\mathrm{g} / \mathrm{mol} .\) (c) Monosodium glutamate (MSG), a flavor enhancer in certain foods, contains \(35.51 \% \mathrm{C}, 4.77 \% \mathrm{H}, 37.85 \% \mathrm{O}\) , \(8.29 \% \mathrm{N},\) and 13.60\(\% \mathrm{Na}\) , and has a molar mass of 169 \(\mathrm{g} / \mathrm{mol} .\)

Hydrogen cyanide, HCN, is a poisonous gas. The lethal dose is approximately 300 \(\mathrm{mg}\) HCN per kilogram of air when inhaled. (a) Calculate the amount of HCN that gives the lethal dose in a small laboratory room measuring \(12 \times 15 \times 8.0 \mathrm{ft}\) . The density of air at \(26^{\circ} \mathrm{C}\) is 0.00118 \(\mathrm{g} / \mathrm{cm}^{3} .\) (b) If the HCN is formed by reaction of \(\mathrm{NaCN}\) with an acid such as \(\mathrm{H}_{2} \mathrm{SO}_{4}\) what mass of NaCN gives the lethal dose in the room? $$ 2 \mathrm{NaCN}(s)+\mathrm{H}_{2} \mathrm{SO}_{4}(a q) \longrightarrow \mathrm{Na}_{2} \mathrm{SO}_{4}(a q)+2 \mathrm{HCN}(g) $$ (c) HCN forms when synthetic fibers containing Orlon or Acrilan burn. Acrilan has an empirical formula of \(\mathrm{CH}_{2} \mathrm{CHCN},\) so HCN is 50.9\(\%\) of the formula by mass. A rug measures \(12 \times 15 \mathrm{ft}\) and contains 30 oz of Acrilan fibers per square yard of carpet. If the rug burns, will a lethal dose of HCN be generated in the room? Assume that the yield of HCN from the fibers is 20\(\%\) and that the carpet is 50\(\%\) consumed.

(a) What is the mass, in grams, of \(2.50 \times 10^{-3}\) mol of ammonium phosphate? (b) How many moles of chloride ions are in 0.2550 g of aluminum chloride? (c) What is the mass, in grams, of \(7.70 \times 10^{20}\) molecules of caffeine, \(\mathrm{C}_{8} \mathrm{H}_{10} \mathrm{N}_{4} \mathrm{O}_{2} ?\) (d) What is the molar mass of cholesterol if 0.00105 \(\mathrm{mol}\) has a mass of 0.406 \(\mathrm{g}\) ?

The semiconductor gallium arsenide, GaAs, is used in high-speed integrated circuits, light-emitting diodes, and solar cells. Its density is 5.32 \(\mathrm{g} / \mathrm{m}^{3} .\) It can be made by reacting trimethylgallium, \(\left(\mathrm{CH}_{3}\right)_{3} \mathrm{Ga},\) with arsine gas, \(\mathrm{AsH}_{3}\) . The other product of the reaction is methane, \(\mathrm{CH}_{4}\) . (a) If you reacted 450.0 g of trimethylgallium with 300.0 \(\mathrm{g}\) of arsine, what mass of GaAs could you make? (b) Which reactant, if any, would be left over, and how many moles of the leftover reactant would remain? (c) One application of GaAs uses it as a thin film. If you take the mass of GaAs from part (a) and make a 40 -nm thin film from it, what area, in \(\mathrm{cm}^{2},\) would it cover? Recall that \(1 \mathrm{nm}=1 \times 10^{-9} \mathrm{m} .\)

An element \(X\) forms an iodide \(\left(\mathrm{XI}_{3}\right)\) and a chloride \(\left(\mathrm{XCl}_{3}\right) .\) The iodide is quantitatively converted to the chloride when it is heated in a stream of chlorine: $$ 2 \mathrm{XI}_{3}+3 \mathrm{Cl}_{2} \longrightarrow 2 \mathrm{XCl}_{3}+3 \mathrm{I}_{2} $$ If 0.5000 \(\mathrm{g}\) of \(\mathrm{XI}_{3}\) is treated with chlorine, 0.2360 \(\mathrm{g}\) of \(\mathrm{XCl}_{3}\) is obtained. (a) Calculate the atomic weight of the element X. (b) Identify the element X.

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