Chapter 3: Problem 71
The combustion of one mole of liquid ethanol, \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{OH}\) , produces 1367 \(\mathrm{kJ}\) of heat. Calculate how much heat is produced when 235.0 \(\mathrm{g}\) of ethanol are combusted.
Chapter 3: Problem 71
The combustion of one mole of liquid ethanol, \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{OH}\) , produces 1367 \(\mathrm{kJ}\) of heat. Calculate how much heat is produced when 235.0 \(\mathrm{g}\) of ethanol are combusted.
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Get started for freeDetermine the empirical formulas of the compounds with the following compositions by mass: $$ \begin{array}{l}{\text { (a) } 55.3 \% \mathrm{K}, 14.6 \% \mathrm{P}, \text { and } 30.1 \% \mathrm{O}} \\ {\text { (b) } 24.5 \% \mathrm{Na}, 14.9 \% \mathrm{Si}, \text { and } 60.6 \% \mathrm{F}} \\ {\text { (c) } 62.1 \% \mathrm{C}, 5.21 \% \mathrm{H}, 12.1 \% \mathrm{N}, \text { and the remainder O }}\end{array} $$
Introduced the idea of structural isomerism, with 1 -propanol and 2 -propanol as examples. Determine which of these properties would distinguish these two substances: (a) boiling point, (b) combustion analysis results, (c) molecular weight, (d) density at a given temperature and pressure. You can check on the properties of these two compounds in Wolfram Alpha (http://www. wolframalpha.com/) or the CRC Handbook of Chemistry and Physics.
Hydrogen sulfide is an impurity in natural gas that must be removed. One common removal method is called the Claus process, which relies on the reaction: $$ 8 \mathrm{H}_{2} \mathrm{S}(g)+4 \mathrm{O}_{2}(g) \longrightarrow \mathrm{S}_{8}(l)+8 \mathrm{H}_{2} \mathrm{O}(g) $$ Under optimal conditions the Claus process gives 98\(\%\) yield of \(S_{8}\) from \(\mathrm{H}_{2}\) . If you started with 30.0 g of \(\mathrm{H}_{2} \mathrm{S}\) and 50.0 \(\mathrm{g}\) of \(\mathrm{O}_{2},\) how many grams of \(\mathrm{S}_{8}\) would be produced, assuming 98\(\%\) yield?
Valproic acid, used to treat seizures and bipolar disorder, is composed of \(\mathrm{C}, \mathrm{H},\) and \(\mathrm{O} . \mathrm{A}\) . \(165-\mathrm{g}\) sample is combusted to produce 0.166 \(\mathrm{g}\) of water and 0.403 \(\mathrm{g}\) of carbon dioxide. What is the empirical formula for valproic acid? If the molar mass is \(144 \mathrm{g} / \mathrm{mol},\) what is the molecular formula?
One of the steps in the commercial process for converting ammonia to nitric acid is the conversion of \(\mathrm{NH}_{3}\) to \(\mathrm{NO} :\) $$ 4 \mathrm{NH}_{3}(g)+5 \mathrm{O}_{2}(g) \longrightarrow 4 \mathrm{NO}(g)+6 \mathrm{H}_{2} \mathrm{O}(g) $$ In a certain experiment, 2.00 \(\mathrm{g}\) of \(\mathrm{NH}_{3}\) reacts with 2.50 \(\mathrm{g}\) of \(\mathrm{O}_{2} .\) (a) Which is the limiting reactant? (b) How many grams of \(\mathrm{NO}\) and \(\mathrm{H}_{2} \mathrm{O}\) form? (c) How many grams of the excess reactant remain after the limiting reactant is completely consumed? (d) Show that your calculations in parts (b) and (c) are consistent with the law of conservation of mass.
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