Complete and balance the following molecular equations, and then write the net ionic equation for each: \begin{equation} \begin{array}{l}{\text { (a) } \operatorname{HBr}(a q)+\mathrm{Ca}(\mathrm{OH})_{2}(a q) \longrightarrow} \\ {\text { (b) } \mathrm{Cu}(\mathrm{OH})_{2}(s)+\mathrm{HClO}_{4}(a q) \longrightarrow} \\\ {\text { (c) } \mathrm{Al}(\mathrm{OH})_{3}(s)+\mathrm{HNO}_{3}(a q) \longrightarrow}\end{array} \end{equation}

Short Answer

Expert verified
The net ionic equations for the given molecular equations are: (a) \(2\mathrm{H}^{+}(a q)+ 2\mathrm{OH}^{-}(a q) \longrightarrow 2\mathrm{H}_{2}\mathrm{O}(l)\) (b) \(\mathrm{Cu}(\mathrm{OH})_{2}(s)+2\mathrm{H}^{+}(a q) \longrightarrow 2\mathrm{H}_{2}\mathrm{O}(l)+\mathrm{Cu}^{2+}(a q)\) (c) \(\mathrm{Al}(\mathrm{OH})_{3}(s)+3\mathrm{H}^{+}(a q) \longrightarrow 3\mathrm{H}_{2}\mathrm{O}(l)+\mathrm{Al}^{3+}(a q)\)

Step by step solution

01

(a) Identify reactants and products

For the reaction \(\operatorname{HBr}(a q)+\mathrm{Ca}(\mathrm{OH})_{2}(a q) \longrightarrow\), the reactants are HBr (hydrobromic acid) and Ca(OH)₂ (calcium hydroxide), which is an acid-base reaction. The products will be water H₂O (l) and a salt, calcium bromide CaBr₂ (aq).
02

(a) Determine balancing coefficients

To balance the equation, we need 2 moles of HBr for every mole of Ca(OH)₂, 2 moles of water H₂O, and 1 mole of CaBr₂.
03

(a) Write balanced molecular equation

The balanced molecular equation is: \[ 2\operatorname{HBr}(a q)+\mathrm{Ca}(\mathrm{OH})_{2}(a q) \longrightarrow 2\mathrm{H}_{2}\mathrm{O}(l)+\mathrm{CaBr}_{2}(a q) \]
04

(a) Write complete ionic equation

The complete ionic equation is: \[ 2\mathrm{H}^{+}(a q)+2\mathrm{Br}^{-}(a q)+\mathrm{Ca}^{2+}(a q)+ 2\mathrm{OH}^{-}(a q) \longrightarrow 2\mathrm{H}_{2}\mathrm{O}(l)+\mathrm{Ca}^{2+}(a q)+ 2\mathrm{Br}^{-}(a q) \]
05

(a) Net ionic equation

Cancel out spectator ions (Br⁻ and Ca²⁺) from both sides: \[ 2\mathrm{H}^{+}(a q)+ 2\mathrm{OH}^{-}(a q) \longrightarrow 2\mathrm{H}_{2}\mathrm{O}(l) \]
06

(b) Identify reactants and products

For the reaction \[\mathrm{Cu}(\mathrm{OH})_{2}(s)+\mathrm{HClO}_{4}(a q) \longrightarrow\], the reactants are Cu(OH)₂ (copper(II) hydroxide) and HClO₄ (perchloric acid), which is another acid-base reaction. The products will be water H₂O (l) and a salt, copper(II) perchlorate Cu(ClO₄)₂ (aq).
07

(b) Determine balancing coefficients

To balance the equation, we need 1 mole of Cu(OH)₂, 2 moles of HClO₄, 2 moles of water H₂O, and 1 mole of Cu(ClO₄)₂.
08

(b) Write balanced molecular equation

The balanced molecular equation is: \[ \mathrm{Cu}(\mathrm{OH})_{2}(s)+2\mathrm{HClO}_{4}(a q) \longrightarrow 2\mathrm{H}_{2}\mathrm{O}(l)+\mathrm{Cu}(\mathrm{ClO}_{4})_{2}(a q) \]
09

(b) Write complete ionic equation

The complete ionic equation is: \[ \mathrm{Cu}(\mathrm{OH})_{2}(s)+2\mathrm{H}^{+}(a q)+2\mathrm{ClO}_{4}^{-}(a q) \longrightarrow 2\mathrm{H}_{2}\mathrm{O}(l)+\mathrm{Cu}^{2+}(a q)+2\mathrm{ClO}_{4}^{-}(a q) \]
10

(b) Net ionic equation

Cancel out spectator ions (ClO₄⁻) from both sides: \[ \mathrm{Cu}(\mathrm{OH})_{2}(s)+2\mathrm{H}^{+}(a q) \longrightarrow 2\mathrm{H}_{2}\mathrm{O}(l)+\mathrm{Cu}^{2+}(a q) \]
11

(c) Identify reactants and products

For the reaction \[\mathrm{Al}(\mathrm{OH})_{3}(s)+\mathrm{HNO}_{3}(a q) \longrightarrow\], the reactants are Al(OH)₃ (aluminum hydroxide) and HNO₃ (nitric acid), which is another acid-base reaction. The products will be water H₂O (l) and a salt, aluminum nitrate Al(NO₃)₃ (aq).
12

(c) Determine balancing coefficients

To balance the equation, we need 1 mole of Al(OH)₃, 3 moles of HNO₃, 3 moles of water H₂O, and 1 mole of Al(NO₃)₃.
13

(c) Write balanced molecular equation

The balanced molecular equation is: \[ \mathrm{Al}(\mathrm{OH})_{3}(s)+3\mathrm{HNO}_{3}(a q) \longrightarrow 3\mathrm{H}_{2}\mathrm{O}(l)+\mathrm{Al}(\mathrm{NO}_{3})_{3}(a q) \]
14

(c) Write complete ionic equation

The complete ionic equation is: \[ \mathrm{Al}(\mathrm{OH})_{3}(s)+3\mathrm{H}^{+}(a q)+3\mathrm{NO}_{3}^{-}(a q) \longrightarrow 3\mathrm{H}_{2}\mathrm{O}(l)+\mathrm{Al}^{3+}(a q)+3\mathrm{NO}_{3}^{-}(a q) \]
15

(c) Net ionic equation

Cancel out spectator ions (NO₃⁻) from both sides: \[ \mathrm{Al}(\mathrm{OH})_{3}(s)+3\mathrm{H}^{+}(a q) \longrightarrow 3\mathrm{H}_{2}\mathrm{O}(l)+\mathrm{Al}^{3+}(a q) \]

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Most popular questions from this chapter

(a) By titration, 15.0 \(\mathrm{mL}\) of 0.1008 \(\mathrm{M}\) sodium hydroxide is needed to neutralize a \(0.2053-\mathrm{g}\) sample of a weak acid. What is the molar mass of the acid if it is monoprotic? (b) An elemental analysis of the acid indicates that it is composed of \(5.89 \% \mathrm{H}, 70.6 \% \mathrm{C},\) and 23.5\(\% \mathrm{O}\) by mass. What is composed of \(5.89 \% \mathrm{H}, 70.6 \% \mathrm{C},\) and 23.5\(\% \mathrm{O}\) by mass. What is its molecular formula?

Tartaric acid, \(\mathrm{H}_{2} \mathrm{C}_{4} \mathrm{H}_{4} \mathrm{O}_{6}\) , has two acidic hydrogens. The acid is often present in wines and a salt derived from the acid precipitates from solution as the wine ages. A solution containing an unknown concentration of the acid is titrated with NaOH. It requires 24.65 \(\mathrm{mL}\) of 0.2500 \(\mathrm{M}\) NaOH solution to titrate both acidic protons in 50.00 \(\mathrm{mL}\) of the tartaric acid solution. Write a balanced net ionic equation for the neutralization reaction, and calculate the molarity of the tartaric acid solution.

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