Chapter 5: Problem 19
Identify the force present and explain whether work is being performed in the following cases: (a) You lift a pencil off the top of a desk. \((\mathbf{b})\) A spring is compressed to half its normal length.
Chapter 5: Problem 19
Identify the force present and explain whether work is being performed in the following cases: (a) You lift a pencil off the top of a desk. \((\mathbf{b})\) A spring is compressed to half its normal length.
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Get started for freeConsider the decomposition of liquid benzene, \(\mathrm{C}_{6} \mathrm{H}_{6}(l),\) to gaseous acetylene, \(\mathrm{C}_{2} \mathrm{H}_{2}(g) :\) $$\mathrm{C}_{6} \mathrm{H}_{6}(l) \longrightarrow 3 \mathrm{C}_{2} \mathrm{H}_{2}(g) \quad \Delta H=+630 \mathrm{kJ}$$ (a) What is the enthalpy change for the reverse reaction? (b) What is \(\Delta H\) for the formation of 1 mol of acetylene? (c) Which is more likely to be thermodynamically favored, the forward reaction or the reverse reaction? (d) If \(\mathrm{C}_{6} \mathrm{H}_{6}(g)\) were consumed instead of \(\mathrm{C}_{6} \mathrm{H}_{6}(l),\) would you expect the magnitude of \(\Delta H\) to increase, decrease, or stay the same? Explain.
(a) What is the value of the standard enthalpy of formation of an element in its most stable form? (b) Write the chemical equation for the reaction whose enthalpy change is the standard enthalpy of formation of sucrose (table sugar), \(\mathrm{C}_{12} \mathrm{H}_{22} \mathrm{O}_{11}(s), \Delta H_{f}^{\circ}\left[\mathrm{C}_{12} \mathrm{H}_{22} \mathrm{O}_{11}(s)\right]\)
Can you use an approach similar to Hess's law to calculate the change in internal energy, \(\Delta E,\) for an overall reaction by summing the \(\Delta E\) values of individual reactions that add up to give the desired overall reaction?
The heat of combustion of ethanol, \(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{OH}(l),\) is \(-1367 \mathrm{kJ} / \mathrm{mol} .\) A batch of Sauvignon Blanc wine contains 10.6\(\%\) ethanol by mass. Assuming the density of the wine to be \(1.0 \mathrm{g} / \mathrm{mL},\) what is the caloric content due to the alcohol (ethanol) in a 6 -oz glass of wine \((177 \mathrm{mL})\) ?
(a) What is meant by the term standard conditions with reference to enthalpy changes? (b) What is meant by the term enthalpy of formation? (c) What is meant by the term standard enthalpy of formation?
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