Chapter 5: Problem 21
(a) Which of the following cannot leave or enter a closed system: heat, work, or matter? (b) Which cannot leave or enter an isolated system? (c) What do we call the part of the universe that is not part of the system?
Chapter 5: Problem 21
(a) Which of the following cannot leave or enter a closed system: heat, work, or matter? (b) Which cannot leave or enter an isolated system? (c) What do we call the part of the universe that is not part of the system?
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Get started for freeFor each of the following compounds, write a balanced thermochemical equation depicting the formation of one mole of the compound from its elements in their standard states and then look up \(\Delta H^{\circ} f\) for each substance in Appendix C. (a) \(\mathrm{NO}_{2}(g),(\mathbf{b}) \mathrm{SO}_{3}(g),(\mathbf{c}) \mathrm{NaBr}(s),(\mathbf{d}) \mathrm{Pb}\left(\mathrm{NO}_{3}\right)_{2}(s) .\)
(a) Use enthalpies of formation given in Appendix \(C\) to calculate \(\Delta H\) for the reaction \(B r_{2}(g) \longrightarrow 2\) Br \((g),\) and use this value to estimate the bond enthalpy \(D(\mathrm{Br}-\mathrm{Br}) .\) (b) How large is the difference between the value calculated in part (a) and the value given in Table 5.4 ?
Without doing any calculations, predict the sign of \(\Delta H\) for each of the following reactions: $$\begin{array}{l}{\text { (a) } 2 \mathrm{NO}_{2}(g) \longrightarrow \mathrm{N}_{2} \mathrm{O}_{4}(g)} \\ {\text { (b) } 2 \mathrm{F}(g) \longrightarrow \mathrm{F}_{2}(g)} \\ {\text { (c) } \mathrm{Mg}^{2+}(g)+2 \mathrm{Cl}^{-}(g) \longrightarrow \mathrm{MgCl}_{2}(s)} \\ {\text { (d) } \mathrm{HBr}(g) \longrightarrow \mathrm{H}(g)+\mathrm{Br}(g)}\end{array}$$
A \(201-\) lb man decides to add to his exercise routine by walking up three flights of stairs \((45 \mathrm{ft}) 20\) times per day. He figures that the work required to increase his potential energy in this way will permit him to eat an extra order of French fries, at 245 Cal, without adding to his weight. Is he correct in this assumption?
For the following processes, calculate the change in internal energy of the system and determine whether the process is endothermic or exothermic: (a) A balloon is cooled by removing 0.655 \(\mathrm{kJ}\) of heat. It shrinks on cooling, and the atmosphere does 382 J of work on the balloon. (b) A 100.0 -g bar of gold is heated from \(25^{\circ} \mathrm{C}\) to \(50^{\circ} \mathrm{C}\) during which it absorbs 322 \(\mathrm{J}\) of heat. Assume the volume of the gold bar remains constant.
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